453556-97-3Relevant articles and documents
Luminescent neutral lanthanide complexes of 5-aryl-2,2′-bipyridine-6-carboxylic acids, synthesis and properties
Krinochkin, Alexey P.,Kopchuk, Dmitry S.,Kozhevnikov, Dmitry N.
, p. 556 - 561 (2015/11/17)
Luminescent lanthanide complexes of 4-aryl-1-(2-pyridyl)-6,7-dihydro-5H-cyclopenta[c]pyridine-3-carboxylic acids and 5-tolyl-2,2′-bipyridine-6-carboxylic acid were prepared. The ligands were synthesized using the "1,2,4-triazine" methodology. In one case, the opportunity of copper complex preparation, followed by exchange of the metal cation from copper to europium to overcome synthetic difficulties, was demonstrated. The ability of tuning the properties of the complexes by means of varying the structure of the ligands was demonstrated. In particular, the introduction of the cyclopentene moiety allowed the preparation of highly soluble complexes in non-polar organic solvents.
Synthesis of functionalised bipyridines by sequential nucleophilic substitution of hydrogen and cycloaddition in 1,2,4-triazine rings
Kozhevnikov, Dmitry N.,Kozhevnikov, Valery N.,Nikitina, Tatiana V.,Rusinov, Vladimir L.,Chupakhin, Oleg N.,Neunhoeffer, Hans
, p. 30 - 32 (2007/10/03)
A new methodology for the synthesis of functionalised bipyridines by the direct cyanation of 3-(2-pyridyl)-1,2,4-triazine 4-oxide through nucleophilic substitution for hydrogen followed by the transformation of the 1,2,4-triazine ring into the pyridine ring by the Diels-Alder reaction and, finally, the chemical conversion of the cyano group is described.
