4541-85-9

Basic information

• Product Name: Benzene, (1-chloro-1-propenyl)-, (Z)-
• CAS NO: 4541-85-9
• Molecular Formula: C9H9Cl
• Molecular Weight: 152.623
• Mol File: 4541-85-9.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzene, (1-chloro-1-propenyl)-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1-chloro-1-propenyl)-, (Z)-(4541-85-9)
• EPA Substance Registry System: Benzene, (1-chloro-1-propenyl)-, (Z)-(4541-85-9)

Safety Data

• Hazardous Substances Data: 4541-85-9(Hazardous Substances Data)

Upstream product

• 93-55-0 1-phenyl-propan-1-one 
• 766-90-5 cis-1-phenyl-1-propylene 
• 109391-76-6 C₁₅H₁₅Cl₃Se 
• 563-58-6 1,1-dichloropropene 
• 673-32-5 1-Phenylprop-1-yne 
• 873-66-5 1-propenylbenzene 
• 507-20-0 tertiary butyl chloride 

Downstream Products

• 6084-17-9 2-chloro-1-phenylpropan-1-one 

Relevant articles and documents

Metal-free transfer hydrochlorination of internal C-C triple bonds with a bicyclo[3.1.0]hexane-based surrogate releasing two molecules of hydrogen chloride

The development and application of a transfer hydrochlorination reagent based on a trichlorinated bicyclo[3.1.0]hexane core that transfers two molecules of HCl per molecule of surrogate to a π-basic substrate under B(C6F5)3 catalysis is reported. Lewis acid-assisted chloride abstraction followed by thermal electrocyclic cyclopropyl-to-allyl cation ring opening releases ring strain as a previously unexploited driving force.

A mild synthesis of vinyl halides and gem-dihalides using triphenyl phosphite-halogen-based reagents

A new application of (PhO)3P-halogen-based reagents to the synthesis of vinyl halides and gem-dihalides is described. Vinyl halides were prepared in good to excellent yields from enolizable ketones, whereas aldehydes afforded the corresponding gem-dihalides. The halogenation proceeded smoothly under mild conditions.

Convenient synthesis of aryl-substituted halo olefins from aromatic ketones and acetyl halides in the presence of silica gel-supported zinc halides

A simple and efficient procedure has been developed for the synthesis of aryl-substituted chloro and bromo olefins from aromatic ketones and acetyl halides in the presence of silica gel-supported zinc halides. The Z-isomer is selectively formed.