454647-00-8

Basic information

• Product Name: 2,4-Hexadienedioic acid, bis[(4-chlorophenyl)methyl] ester, (2Z,4Z)-
• CAS NO: 454647-00-8
• Molecular Formula: C20H16Cl2O4
• Molecular Weight: 391.251
• Mol File: 454647-00-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2,4-Hexadienedioic acid, bis[(4-chlorophenyl)methyl] ester, (2Z,4Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Hexadienedioic acid, bis[(4-chlorophenyl)methyl] ester, (2Z,4Z)-(454647-00-8)
• EPA Substance Registry System: 2,4-Hexadienedioic acid, bis[(4-chlorophenyl)methyl] ester, (2Z,4Z)-(454647-00-8)

Safety Data

• Hazardous Substances Data: 454647-00-8(Hazardous Substances Data)

Upstream product

• 1119-72-8 cis,cis-Muconic acid 
• 622-95-7 4-chlorobenzyl bromide 
• 873-76-7 para-Chlorobenzyl alcohol 
• 66415-44-9 (Z,Z)-muconic acid dichloride 

Relevant articles and documents

Stereospecific radical polymerization of substituted benzyl muconates in the solid state under topochemical control

We have successfully controlled the stereochemical structure of diene polymers during radical polymerization in the solid state under UV and γ-ray radiation. The polymerization of the substituted benzyl muconates occurred via a crystal lattice controlled reaction mechanism. The polymerization is controlled by not only diisotactic and disyndiotactic, but also meso and racemo structures to afford various kinds of stereoregular polymers. Georg Thieme Verlag Stuttgart.

Two-step and reversible phase transitions of organic polymer crystals produced by topochemical polymerization

We describe here the novel phase transition of organic polymer crystals that are directly fabricated by the topochemical polymerization of the 4-bromo- and 4-chlorobenzyl esters of (Z,Z)-muconic acid as the 1,3-diene monomers in the crystalline state. The