45700-12-7Relevant articles and documents
Thermal C-H Activation Catalyzed by RhCl(CH2=CH2)(PMe3)2. Hydrogen Transfer from Cycloalkanes to Ethylene and Ethylene Insertion into Cycloalkanes
Sakakura, Toshiyasu,Tanaka, Masato
, p. 359 - 362 (1991)
Dehydrogenation of cycloalkanes to cycloalkenes is catalyzed by RhCl(CH2=CH2)(PMe3)2 under ethylene pressure at a high temperature over 170 deg C.Ethylene insertion into sp3 C-H bond of cycloalkanes occurs at 230 deg C to afford ethylcycloalkanes.