4591-40-6

Basic information

• Product Name: 2-PHENOXY-1,3,2-BENZODIOXAPHOSPHOLE
• Synonyms: 2-PHENOXY-1,3,2-BENZODIOXAPHOSPHOLE
• CAS NO: 4591-40-6
• Molecular Formula: C₁₂H₉O₃P
• Molecular Weight: 232.171821
• Mol File: 4591-40-6.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 249.8°Cat760mmHg
• Flash Point: 124.5°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 0.0355mmHg at 25°C
• CAS DataBase Reference: 2-PHENOXY-1,3,2-BENZODIOXAPHOSPHOLE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-PHENOXY-1,3,2-BENZODIOXAPHOSPHOLE(4591-40-6)
• EPA Substance Registry System: 2-PHENOXY-1,3,2-BENZODIOXAPHOSPHOLE(4591-40-6)

Safety Data

• Hazardous Substances Data: 4591-40-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H9O3P/c1-2-6-10(7-3-1)13-16-14-11-8-4-5-9-12(11)15-16/h1-9H

Upstream product

• 1641-40-3 pyrocatechol phosphorochloridite 
• 108-95-2 phenol 
• 3426-89-9 phenyl phosphorodichloridite 
• 120-80-9 benzene-1,2-diol 
• 5382-00-3 Diphenyl phosphorochloridite 
• 20621-24-3 N,N-diethyl-3-methyl-1,3,2-benzoaxaphosphol-2(3H)-amine 

Downstream Products

• 108668-92-4 Phenyl-o-phenylenthiophosphat 
• 54622-74-1 C₁₈H₂₁O₅P 
• 53799-42-1 2-Phenoxy-2,2-o-phenylendioxy-4,5-bis-(trifluormethyl)-2,2-dihydro-1,3,2-dioxaphospholen 
• 54622-75-2 C₁₈H₉F₁₂O₅P 
• 52961-95-2 2-phenoxy-2-oxo-4,5-benzo-1,3,2-dioxaphospholane 
• 75-65-0 tert-butyl alcohol 
• 13121-31-8 2-tert-butoxy-4,5-benzo-1,3,2-dioxaphospholane 
• 67-64-1 acetone 
• 108-95-2 phenol 
• 75080-74-9 2-phenoxyspiro<1,3,2λ⁵-benzodioxaphosphole-2,2'(3'H)-<1,3,2,λ⁵>benzoxazaphosphole> 
• 74927-66-5 C₃₆H₂₈N₂O₆P₂ 
• 19579-02-3 2-phenoxy-2,2'-spirobi<1,3,2λ⁵-benzodioxaphosphole> 
• 1641-40-3 pyrocatechol phosphorochloridite 
• 60011-08-7 2,2-Dichloro-2-phenoxy-1,3-dioxa-2λ⁵-phospha-indan 

Relevant articles and documents

Reactions of N-aroxycarbonyltrichloroacetimidates with nucleophilic phosphorus derivatives

Aryl N-aroxycarbonyltrichloroacetimidates (Ar = Ph, 4-FC6H 4) react with diphenylphosphinite according to the scheme of the aza-Perkow reaction to give the corresponding aryl N-(1-aroxy-2,2-dichloro- vinyl)-N-diphenylphosphinoylcarba

Organophosphorus Antioxidants. X. The Hydroperoxide Decomposing Action of Phosphites, Phosphonites and Thiophosphites

The kinetics and mechanism of reactions of phosphites, phosphonites, thiophosphites and hydrogenphosphites with cumyl (CHP), t-butyl (TBHP) and α-tetralyl (THP) hydrogenperoxides has been studied by means of (31)P-n.m.r. spectroscopy, high performance liquid chromatography and iodometric titration.All three valent phosphorus compounds studied initially react with hydroperoxides stoichiometrically to give the corresponding P=O products and alcohol.Some species are able to decompose cumyl hydroperoxide catalytically to form phenol and aceton.Acyloin phosphites decompose CHP catalytically after a stoichiometric reaction as thiophosphites do.Tetramethylpiperidinyl phosphites ("HALS-phosphites") react with hydroperoxides only stoichiometrically but with high velocity.Phosphonites react with hydroperoxides in the same way as the corresponding phosphites.Their reactivity, however, is much higher.Hydrogenphosphites are less reactive than phosphites in the reaction with hydroperoxides.They are able to act catalytically.