46117-36-6Relevant articles and documents
Facile aluminum(III) chloride catalyzed preparation of β,γ-unsaturated O-aryl esters from allylsilanes and aryl chloroformates
Olah,Van Vliet,Wang,Prakash
, p. 159 - 161 (1995)
The aluminum trichloride catalyzed reaction of phenyl chloroformate (1a) with allylsilanes 2a-e gives phenyl 3-alkenoates in excellent yields. The reaction with allyltrimethylsilane 2a also works with a number of para substituted aryl chloroformates 1b-f.
Copper-catalyzed asymmetric cyanation of alkenes via carbonyl-assisted coupling of alkyl-substituted carbon-centered radicals
Zhou, Song,Zhang, Guoyu,Fu, Liang,Chen, Pinhong,Li, Yibiao,Liu, Guosheng
supporting information, p. 6299 - 6303 (2020/10/02)
Based on a copper-catalyzed radical relay strategy, the first copper-catalyzed asymmetric cyanation of alkyl-substituted alkenes has been developed. The reaction, featuring mild reaction conditions and excellent functional group compatibilities, provides
Gold-catalyzed intramolecular hydroarylation of olefins. Scope evaluation and preliminary mechanistic studies
Jean, Mickael,Van De Weghe, Pierre
supporting information; experimental part, p. 3509 - 3513 (2011/07/09)
We report a gold-catalyzed intramolecular hydroarylation of unactivated olefins using a combination of AuCl3/AgOTf as the catalytic system affording dihydrobenzopyrans, tetralins and tetrahydroquinolines in good yields. For our preliminary mechanistic studies, we have investigated the kinetic isotope effects with deuterated arene compounds and found that this catalytic hydroarylation is consistent with an electrophilic aromatic substitution process.
