4639-78-5

Basic information

• Product Name: Benzenemethanol, a-phenyl-a-(triphenylgermyl)-
• CAS NO: 4639-78-5
• Molecular Formula: C31H26GeO
• Molecular Weight: 487.137
• Mol File: 4639-78-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-phenyl-a-(triphenylgermyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-phenyl-a-(triphenylgermyl)-(4639-78-5)
• EPA Substance Registry System: Benzenemethanol, a-phenyl-a-(triphenylgermyl)-(4639-78-5)

Safety Data

• Hazardous Substances Data: 4639-78-5(Hazardous Substances Data)

Upstream product

• 119-61-9 benzophenone 
• 2816-43-5 triphenylgermane 
• 623-73-4 diazoacetic acid ethyl ester 
• 1074-29-9 trichlorophenylgermane 
• 100-52-7 benzaldehyde 
• 100-58-3 phenylmagnesium bromide 
• 591-51-5 phenyllithium 
• 83447-99-8 GeCl₃COC₆H₅ 

Relevant articles and documents

ASSISTANCE NUCLEOPHILE DANS DES REACTIONS DE REDUCTION D'ORGANOHALOGENO- ET HALOGENO-GERMANES PAR DES REDUCTEURS DOUX R3M(IVB)-H ET RCHO: GERMYLANIONS, DERIVES FONCTIONNELS DU GERMANIUM

Catalytic activity of nuclophiles such as tertiary amines and diazo derivatives in the reduction of halogermanes by means of gentle reductive agents, such as R3M(IVB)-H or RCHO, has been shown.In the particular case of enolisable aldehyde, a competition between nucleophilic substitution at the metal and germanium-halogen bond reduction has been observed.Transposition of enoxygermanes formed through the substitution process, leads to β-germylaldehydes.