47157-01-7

Basic information

• Product Name: 2,6-DIBENZYLPHENOL
• Synonyms: 2,6-DIBENZYLPHENOL;TIMTEC-BB SBB008562;2,6-Dibenylphenol;2,6-DIBENZYLPHENOL ---CRYSTALLINE---;2,6-Bis(phenylmethyl)phenol
• CAS NO: 47157-01-7
• Molecular Formula: C₂₀H₁₈O
• Molecular Weight: 274.36
• Mol File: 47157-01-7.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 421.3 °C at 760 mmHg
• Flash Point: 199.4 °C
• Appearance: /
• Density: 1.112 g/cm³
• Vapor Pressure: 1.08E-07mmHg at 25°C
• Refractive Index: 1.621
• CAS DataBase Reference: 2,6-DIBENZYLPHENOL(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-DIBENZYLPHENOL(47157-01-7)
• EPA Substance Registry System: 2,6-DIBENZYLPHENOL(47157-01-7)

Safety Data

• Hazardous Substances Data: 47157-01-7(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 15, p. 1263, 1974 DOI: 10.1016/S0040-4039(01)82462-X

InChI:InChI=1/C20H18O/c21-20-18(14-16-8-3-1-4-9-16)12-7-13-19(20)15-17-10-5-2-6-11-17/h1-13,21H,14-15H2

Upstream product

• 78429-79-5 benzyl-(2-benzyl-phenyl)-ether 
• 139-02-6 sodium phenoxide 
• 100-44-7 benzyl chloride 
• 108-88-3 toluene 
• 108-95-2 phenol 
• 897-78-9 2,6-bis(phenylmethylene)cyclohexanone 
• 100-51-6 benzyl alcohol 
• 22040-04-6 2-Benzyl-6-methylphenyl-phenylether 
• 253610-05-8 2,6-dibenzylanisole 
• 1208-45-3 2-benzyl-6-methylphenol 
• 95-48-7 ortho-cresol 
• 100-39-0 benzyl bromide 
• 28994-41-4 o-Benzylphenol 
• 131628-72-3 3-benzyl-2-hydroxybenzaldehyde 

Downstream Products

• 14073-36-0 5-Nitro-2-hydroxy-1.3-dibenzyl-benzol 
• 102599-31-5 acetic acid-(2,6-dibenzyl-phenyl ester) 
• 102001-55-8 2,6-dibenzylcyclohexa-2,5-diene-1,4-dione 
• 14006-28-1 4-Acetamino-2,6-dibenzyl-anisol 
• 14006-29-2 2,6-dibenzyl-4-nitro-anisole 
• 879410-74-9 [Eu2(μ-2,6-dibenzylphenol(-H))2(2,6-debenzylphenol(-H))2] 

Relevant articles and documents

-

-

Towards ortho-selective electrophilic substitution/addition to phenolates in anhydrous solvents

Alkyl-substituted Li-phenolates with BnBr in water solution lead to a mixture of o- and p-Bn-substituted phenols together with a substantial amount of phenol Bn ether. In CPME, and especially in toluene with 1–2 equivalents of ether or alcohol additives, ortho-selective alkylation is achieved. In the case of o,o,p-tri- and o,o-di-substituted phenols dearomatization occurs affording o-Bn-substituted alkyl cyclohexadienones with yields up to 92% with an o/p ratio up to 90/1.

METHOD OF MAKING BENZYLATED PHENOLS

A method of making benzylated phenols comprises contacting a phenol and a benzyl alcohol with a basic metal oxide catalyst at a temperature sufficient to maintain each of the phenol and the benzyl alcohol in a vapor phase. The phenol has at least one hydr