473611-23-3Relevant articles and documents
Iridium-Catalyzed Asymmetric Transfer Hydrogenation of Alkynyl Ketones Using Sodium Formate and Ethanol as Hydrogen Sources
Zhang, Yang-Ming,Yuan, Ming-Lei,Liu, Wei-Peng,Xie, Jian-Hua,Zhou, Qi-Lin
supporting information, p. 4486 - 4489 (2018/08/09)
A green and efficient iridium-catalyzed asymmetric transfer hydrogenation of alkynyl ketones to chiral propargylic alcohols has been developed. By using sodium formate and ethanol as hydrogen sources, a series of alkynyl ketones were hydrogenated by chira
Development of a co-mediated rearrangement reaction
Carbery, David R.,Reignier, Serge,Myatt, James W.,Miller, Neil D.,Harrity, Joseph P. A.
, p. 2584 - 2587 (2007/10/03)
Simultaneous generation of an enolate and Nicholas carbocation unit (2) occurs on treatment of enol ether-cobalt complexes 1 with Lewis acids (X). Subsequent cyclization provides α-functionalized β-alkynyl cycloalkanones 3 in a regiospecific fashion. The