474003-61-7

Basic information

• Product Name: 5-Hexenal, 6-phenyl-, O-[(1,1-dimethylethyl)dimethylsilyl]oxime
• CAS NO: 474003-61-7
• Molecular Formula: C18H29NOSi
• Molecular Weight: 303.52
• Mol File: 474003-61-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-Hexenal, 6-phenyl-, O-[(1,1-dimethylethyl)dimethylsilyl]oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Hexenal, 6-phenyl-, O-[(1,1-dimethylethyl)dimethylsilyl]oxime(474003-61-7)
• EPA Substance Registry System: 5-Hexenal, 6-phenyl-, O-[(1,1-dimethylethyl)dimethylsilyl]oxime(474003-61-7)

Safety Data

• Hazardous Substances Data: 474003-61-7(Hazardous Substances Data)

Upstream product

• 98078-15-0 6-phenylhex-5-en-1-ol 
• 1100-88-5 benzyltriphenylphosphonium chloride 
• 53847-18-0 6-phenyl-5-hexenal 
• 694-54-2 tetrahydro-2H-2-pyranol 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Relevant articles and documents

Intramolecular cycloaddition of O-tert-butyldimethylsilyloximes in the presence of BF3-OEt2

Intramolecular cycloaddition of novel 1,3-dipoles, N-boranonitrones, was examined. Treatment of O-tert-butyldimethylsilyloximes 9-12 having olefin moieties with 2 equiv of BF3·OEt2 generated N-boranonitrones, which underwent intramolecular cycloaddition to afford N-nonsubstituted cycloadducts 16 (and/or 18) after extractive workup. Despite the Lewis-acidic conditions, the olefin geometry of the substrates was retained in the cycloadducts in the present cycloaddition. The electronic nature of the N-boranonitrones appeared to be electrophilic. In the case of substrate 11c, having an electron-donating methyl group at an internal position of the olefin moiety, the cycloaddition gave the bridged cycloadduct 18b. The cycloaddition proceeded at relatively low temperature, and the diastereoselectivity was high.