474654-18-7

Basic information

• Product Name: N-[(R)-(4-chlorophenyl)phenylMethyl]ForMaMide
• Synonyms: N-[(R)-(4-chlorophenyl)phenylMethyl]ForMaMide;N-[(R)-^a-(4-Chlorophenyl)benzyl]forMaMide, 98%;N-[(R)-alpha-(4-Chlorophenyl)benzyl]formamide
• CAS NO: 474654-18-7
• Molecular Formula: C₁₄H₁₂ClNO
• Molecular Weight: 245.70418
• Mol File: 474654-18-7.mol
• Article Data: 2

Chemical Properties

• Appearance: /Solid
• CAS DataBase Reference: N-[(R)-(4-chlorophenyl)phenylMethyl]ForMaMide(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(R)-(4-chlorophenyl)phenylMethyl]ForMaMide(474654-18-7)
• EPA Substance Registry System: N-[(R)-(4-chlorophenyl)phenylMethyl]ForMaMide(474654-18-7)

Safety Data

• Hazardous Substances Data: 474654-18-7(Hazardous Substances Data)

Upstream product

• 1078-58-6 diphenylzinc 
• 474654-19-8 N-[(4-chlorophenyl)(phenyl)methyl]formamide 

Downstream Products

• 163837-57-8 (R)-(4-chlorophenyl)(phenyl)methylamine 

Relevant articles and documents

Stereospecific Suzuki-Miyaura coupling of chiral α-(Acylamino) benzylboronic esters with inversion of configuration

The first invertive B-alkyl Suzuki-Miyaura coupling has been achieved. The coupling of enantioenriched α-(acylamino)benzylboronic esters with aryl bromides and chlorides took place efficiently in toluene at 80 °C in the presence of Pd(dba)2 (5 mol %), XPhos (10 mol %), K 2CO3 (3 equiv), and H2O (2 equiv). The reaction proceeded with inversion of configuration to give diarylmethanamine derivatives in high yields with high conservation of enantiomeric excesses.