477952-41-3

Basic information

• Product Name: Carbamic acid, (5-methyl-5-nitro-4-oxohexyl)(phenylmethyl)-, 1,1-dimethylethyl ester
• CAS NO: 477952-41-3
• Molecular Formula: C19H28N2O5
• Molecular Weight: 364.442
• Mol File: 477952-41-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Carbamic acid, (5-methyl-5-nitro-4-oxohexyl)(phenylmethyl)-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (5-methyl-5-nitro-4-oxohexyl)(phenylmethyl)-, 1,1-dimethylethyl ester(477952-41-3)
• EPA Substance Registry System: Carbamic acid, (5-methyl-5-nitro-4-oxohexyl)(phenylmethyl)-, 1,1-dimethylethyl ester(477952-41-3)

Safety Data

• Hazardous Substances Data: 477952-41-3(Hazardous Substances Data)

Upstream product

• 24424-99-5 di-tert-butyl dicarbonate 
• 117654-86-1 4-[N-(t-butoxycarbonyl)-N-[(phenyl)methyl]-amino]butan-1-ol 
• 100-46-9 benzylamine 
• 59578-63-1 4-(benzylamino)-1-butanol 
• 19340-88-6 N-benzyl-4-hydroxybutanamide 
• 213772-31-7 4-[N-benzyl-N-(tert-butyloxycarbonyl)]-amino-1-butanal 
• 477952-40-2 6-[N-benzyl-N-(tert-butyloxycarbonyl)]amino-3-hydroxy-2-methyl-2-nitrohexane 

Downstream Products

• 904325-36-6 (4R)-N-benzyl-N-(tert-butyloxycarbonyl)-4-diethylphosphatoxy-5-methyl-5-nitrohexylamine 
• 41720-99-4 (S)-(-)-2-(1-methylethyl)-pyrrolidine 
• 615268-28-5 (4R)-4-diphenylphosphatoxy-N-prop-2-ynyl-5-methyl-5-nitrohexylamine 
• 615268-43-4 (4R)-N-(tert-butyloxycarbonyl)-4-diphenylphosphatoxy-5-methyl-5-nitrohexylamine 
• 615268-44-5 (4R)-N-(tert-butyloxycarbonyl)-N-prop-2-ynyl-4-diphenylphosphatoxy-5-methyl-5-nitrohexylamine 
• 477952-43-5 (syn/anti)-6-[N-benzyl-N(tert-butyloxycarbonyl)]amino-2,4-dimethyl-2-nitro-3-hexanol 
• 615268-24-1 (S)-1-benzyl-2-isopropyl-pyrrolidine 
• 615268-29-6 (7S)-1,1-dimethyl-2-methylenepyrrolizidine 
• 615268-29-6 (7R)-1,1-dimethyl-2-methylenepyrrolizidine 
• 615268-18-3 (4R)-N-benzyl-N-(tert-butyloxycarbonyl)-4-hydroxy-5-methyl-5-nitro-hexylamine 

Relevant articles and documents

Enantioselective alkene radical cations reactions

The reaction of enantiomerically enriched 2-methyl-2-nitro-3-(diphenylphosphatoxy)alkyl radicals with tributyltin hydride and AIBN in benzene at reflux results in the formation of alkene radical cation/anion pairs, which are trapped intramolecularly by am

Enantioselective cyclization of alkene radical cations

(Matrix Presented) Enantiomerically enriched β-(diphenylphosphatoxy) nitroalkanes undergo radical ionic fragmentation, induced by tributyltin hydride and AIBN in benzene at reflux, to give alkene radical cations in contact radical ion pairs. These contact