478703-05-8

Basic information

• Product Name: 5-hydroxy(²H₂)methyl-1,2,3-trimethoxybenzene
• Synonyms: 5-hydroxy(²H₂)methyl-1,2,3-trimethoxybenzene
• CAS NO: 478703-05-8
• Molecular Weight: 200.203
• Mol File: 478703-05-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-hydroxy(²H₂)methyl-1,2,3-trimethoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 5-hydroxy(²H₂)methyl-1,2,3-trimethoxybenzene(478703-05-8)
• EPA Substance Registry System: 5-hydroxy(²H₂)methyl-1,2,3-trimethoxybenzene(478703-05-8)

Safety Data

• Hazardous Substances Data: 478703-05-8(Hazardous Substances Data)

Upstream product

• 6178-44-5 ethyl 3,4,5-trimethoxybenzoate 
• 118-41-2 Eudesmic acid 
• 1916-07-0 3,4,5-trimethoxybenzoic acid methyl ester 

Downstream Products

• 1031683-94-9 3,4,5-trimethoxybenzaldehyde-α-d₁ 
• 530-55-2 2,6-dimethoxy-p-quinone 
• 86-81-7 3,4,5-trimethoxy-benzaldehyde 
• 478703-13-8 C₉H₉⁽²⁾H₃O₄ 
• 478703-09-2 C₁₀H₁₁⁽²⁾H₃O₃ 
• 131135-40-5 2,3-dimethoxy-5-[D₃-methyl]-1,4-benzoquinone 
• 105801-92-1 2-((all-E)-1,1-dideuterio-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-trideuteriomethyl-[1,4]benzoquinone 
• 478703-06-9 C₁₀H₁₁⁽²⁾H₂BrO₃ 

Relevant articles and documents

Differences in the Mechanisms of MnO2Oxidation between Lignin Model Compounds with the p-Hydroxyphenyl, Guaiacyl, and Syringyl Nuclei

The purpose of this study was to examine how the rate and mechanism of MnO2 oxidation differ between the p-hydroxyphenyl (H), guaiacyl (G), and syringyl (S) types of simple nonphenolic lignin model compounds as well as the p-ethylphenyl (E) type compounds. The oxidation was conducted using an excess amount of MnO2 in a sulfate buffer solution at a pH value of 1.5 at room temperature. MnO2 oxidized at least the G and S nuclei, although it commonly oxidizes alcohols present at the benzyl position. The oxidation rates of the benzyl alcohol derivatives were in the order of G- > S- ? H- > E-type, which suggests that the rates are determined by the electronic effects of their methoxy and ethyl functional groups on not only their benzyl positions but also their aromatic π-electron systems. The kinetic isotope effect was observed in the MnO2 oxidations of the same derivatives deuterated at their benzyl hydroxymethyl groups. The observed magnitudes were in the order of E- ? H- > G- ? S-type, suggesting that the contribution of oxidation of their aromatic nuclei, which is another reaction mode of the oxidation of their benzyl positions, increases in the reverse order.