4856-95-5 Usage
Description
Morpholineborane, also known as Borane morpholine complex, is a colorless to white crystalline powder with unique chemical properties. It is a borane complex that serves as a reducing agent, particularly useful in acid media where other reducing agents like sodium borohydride are ineffective due to their instability.
Uses
Used in Chemical Synthesis:
Morpholineborane is used as a reducing agent for the synthesis of various compounds, including aldehydes and ketones. It is particularly effective in acid media where other reducing agents fail to perform due to their instability.
Used in Fossil Fuel and Steam Systems:
In the energy industry, Morpholineborane is used as a pH adjustment additive, functioning as a corrosion inhibitor in fossil fuel and steam systems. This application helps to protect equipment and infrastructure from the damaging effects of corrosion, thereby extending their lifespan and ensuring efficient operation.
Used in Ethanolysis:
Morpholineborane is involved in the ethanolysis process, where it produces a reducing system. This process is crucial for the synthesis of various chemicals and materials.
Used in the Synthesis of Rh Nanoparticle/Carbon Nanotube Catalysts:
Morpholineborane serves as a reducing agent in the synthesis of Rh nanoparticle and carbon nanotube catalysts. These catalysts are essential in various chemical reactions and industrial processes, contributing to the production of a wide range of products.
Used in the Reduction of Steroidal Ketones:
In the pharmaceutical industry, Morpholineborane is utilized for the stereoselective and regioselective reduction of steroidal ketones. This selective reduction is vital for the synthesis of specific steroidal compounds with desired properties and applications.
Used in Methanolic Cleavage:
Morpholineborane is also employed in the methanolic cleavage process, where it aids in the breaking down of certain chemical bonds. This application is significant in the synthesis of various organic compounds and materials.
Check Digit Verification of cas no
The CAS Registry Mumber 4856-95-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,8,5 and 6 respectively; the second part has 2 digits, 9 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 4856-95:
(6*4)+(5*8)+(4*5)+(3*6)+(2*9)+(1*5)=125
125 % 10 = 5
So 4856-95-5 is a valid CAS Registry Number.
InChI:InChI=1/C4H9NO.B.3H/c1-3-6-4-2-5-1;;;;/h5H,1-4H2;;;;/q;+3;3*-1
4856-95-5Relevant articles and documents
Activation of sodium borohydride via carbonyl reduction for the synthesis of amine- And phosphine-boranes
Hamann, Henry J.,Lin, Randy,Veeraraghavan Ramachandran, P.
supporting information, p. 16770 - 16774 (2021/12/08)
A highly versatile synthesis of amine-boranes via carbonyl reduction by sodium borohydride is described. Unlike the prior bicarbonate-mediated protocol, which proceeds via a salt metathesis reaction, the carbon dioxide-mediated synthesis proceeds via reduction to a monoformatoborohydride intermediate. This has been verified by spectroscopic analysis, and by using aldehydes and ketones as the carbonyl source for the activation of sodium borohydride. This process has been used to produce borane complexes with 1°-, 2°-, and 3°-amines, including those with borane reactive functionalities, heteroarylamines, and a series of phosphines.
Amine-boranes as Dual-Purpose Reagents for Direct Amidation of Carboxylic Acids
Choudhary, Shivani,Hamann, Henry J.,Ramachandran, P. Veeraraghavan
supporting information, (2020/11/13)
Amine-boranes serve as dual-purpose reagents for direct amidation, activating aliphatic and aromatic carboxylic acids and, subsequently, delivering amines to provide the corresponding amides in up to 99% yields. Delivery of gaseous or low-boiling amines as their borane complexes provides a major advantage over existing methodologies. Utilizing amine-boranes containing borane incompatible functionalities allows for the preparation of functionalized amides. An intermolecular mechanism proceeding through a triacyloxyborane-amine complex is proposed.
PREPARATION OF AMINE-BORANES, INCLUDING AMMONIA BORANE
-
, (2016/05/10)
Disclosed herein is a method for preparing amine-boranes.
