485815-56-3

Basic information

• Product Name: 1,3,5-tri[(6'-ethoxycarbonyl-2,2'-bipyridine-5-yl)methoxy]benzene
• Synonyms: 1,3,5-tri[(6'-ethoxycarbonyl-2,2'-bipyridine-5-yl)methoxy]benzene
• CAS NO: 485815-56-3
• Molecular Weight: 846.896
• Mol File: 485815-56-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,3,5-tri[(6'-ethoxycarbonyl-2,2'-bipyridine-5-yl)methoxy]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-tri[(6'-ethoxycarbonyl-2,2'-bipyridine-5-yl)methoxy]benzene(485815-56-3)
• EPA Substance Registry System: 1,3,5-tri[(6'-ethoxycarbonyl-2,2'-bipyridine-5-yl)methoxy]benzene(485815-56-3)

Safety Data

• Hazardous Substances Data: 485815-56-3(Hazardous Substances Data)

Upstream product

• 108-73-6 3,5-dihydroxyphenol 
• 372520-83-7 ethyl 5'-bromomethyl-6-(2,2'-bipyridine)-carboxylate 
• 314767-95-8 ethyl 5'-methyl-6-(2,2'-bipyridine)carboxylate 
• 189195-41-3 5-methyl-2-(tri-n-butylstannyl)pyridine 
• 21190-88-5 6-bromopyridine-2-carboxylic acid ethyl ester 

Relevant articles and documents

Carboxylate derivatives of oligopyridines bearing bromomethyl groups

The synthesis of various oligopyridines possessing a carboxylate and at least one bromoethyl group is reported. The bipyridine and terpyridine cores were constructed in good yields via a Stille cross-coupling, starting from bromopicolines and ethyl bromopicolinate. The bromomethyl function was obtained by free radical bromination using NBS in benzene or bromine in benzene/water biphasic mixture. The building of two model podands by nucleophilic displacement of benzylic bromine by an amine or by a phenol group is described.