4860-03-1Relevant articles and documents
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Tuettschew
, p. 406 (1860)
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METHOD FOR PRODUCING REDUCED HALIDE COMPOUND HAVING UNDERGONE REDUCTION OF CARBON-CARBON UNSATURATED BOND
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Paragraph 0160; 0161; 0162; 0163; 0164; 0165, (2019/11/05)
A halide compound having one or more carbon-carbon unsaturated bonds is catalytically reduced with substantially no dehalogenation to produce a reduced halide compound in which at least one of the one or more unsaturated bonds is reduced. Specifically provided is a method for producing a reduced halide compound including steps of: reacting a nickel compound, a zinc compound, and a borohydride compound in a solvent to obtain a reduction catalyst; and subjecting a halide compound having one or more carbon-carbon unsaturated bonds to catalytic reduction in the presence of the reduction catalyst to reduce at least one of the one or more carbon-carbon unsaturated bonds to thereby obtain a reduced halide compound.
Pivaloyl chloride/DMF: a new reagent for conversion of alcohols to chlorides
Dubey, Abhishek,Upadhyay, Arun K.,Kumar, Pradeep
experimental part, p. 744 - 746 (2010/04/05)
An efficient procedure for conversion of alcohols into the corresponding chlorides is described. Pivaloyl chloride/DMF complex is employed as a mild and inexpensive reagent. A possible reaction mechanism is proposed.