488151-80-0

Basic information

• Product Name: Carbonic acid, 3-(4-methoxyphenyl)-2-propenyl methyl ester
• CAS NO: 488151-80-0
• Molecular Formula: C12H14O4
• Molecular Weight: 222.241
• Mol File: 488151-80-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Carbonic acid, 3-(4-methoxyphenyl)-2-propenyl methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonic acid, 3-(4-methoxyphenyl)-2-propenyl methyl ester(488151-80-0)
• EPA Substance Registry System: Carbonic acid, 3-(4-methoxyphenyl)-2-propenyl methyl ester(488151-80-0)

Safety Data

• Hazardous Substances Data: 488151-80-0(Hazardous Substances Data)

Upstream product

• 24393-56-4 ethyl p-methoxycinnamate 
• 123-11-5 4-methoxy-benzaldehyde 
• 53484-50-7 p-methoxycinnamyl alcohol 
• 79-22-1 methyl chloroformate 

Downstream Products

• 1202397-20-3 (S)-1-methoxy-4-(1-(methylsulfonyl)allyl)benzene 
• 1202397-18-9 (S)-1-chloro-4-(1-(4-methoxyphenyl)allylsulfonyl)benzene 
• 1202397-06-5 (S)-1-methoxy-4-(1-(phenylsulfonyl)allyl)benzene 
• 1202397-23-6 (S)-1-(1-(isopropylsulfonyl)allyl)-4-methoxybenzene 
• 1202397-26-9 (S)-1-(1-(cyclohexylsulfonyl)allyl)-4-methoxybenzene 
• 1196721-84-2 C₂₃H₂₁FO₅S₂ 
• 189884-50-2 (+)-2-[1-(4-methoxy-phenyl)-allyl]-malonic acid dimethyl ester 
• 5706-14-9 2-[(E)-4-methoxyphenylmethylidene]-1-indanone 
• 1222181-30-7 3-(4-methoxyphenyl)-2-methylene-2,3-dihydro-1H-inden-1-one 
• 1208401-82-4 C₁₆H₁₆O₃S 
• 1166198-96-4 N,N-diphenyl-2-(2'-(4-methoxyphenyl)cyclopropyl)propanamide 

Relevant articles and documents

Intramolecular Sakurai Allylation of Geminal Bis(silyl) Enamide with Indolenine. A Diastereoselective Cyclization to Form Functionalized Hexahydropyrido[3,4- b]Indole

A fluoride-promoted intramolecular Sakurai allylation of geminal bis(silyl) enamide with indolenine has been developed. The reaction facilitates an efficient cyclization to give hexahydropyrido[3,4-b]indoles in good yields with high diastereoselectivity. The resulted cis, trans-stereochemistry further enables the ring-closing metathesis (RCM) reaction of two alkene moieties, giving a tetracyclic N-hetereocycle widely found as the core structure in akuammiline alkaloids.

Iridium-Catalyzed Propenylation Reactions for the Synthesis of 4-Pyridone Derivatives

Herein we report an iridium-catalyzed propenylation reaction of allylic carbonates with 4-hydroxypyridine derivatives. The process efficiently provides 4-pyridone derivatives with high stereoselectivities under mild conditions. The products could constitute valuable building blocks for the synthesis of natural products and other bioactive molecules. Preliminary mechanistic studies indicated that a tandem allylic substitution/isomerization reaction occurs to afford the propenylation products. (Figure presented.).

Electrochemical carboxylation of benzylic carbonates: Alternative method for efficient synthesis of arylacetic acids

Electrochemical carboxylation of benzylic carbonates was successfully performed as an alternative method for the synthesis of phenylacetic acids by using a one-compartment cell equipped with a Pt plate cathode and an Mg rod anode in CH3CN to afford the corresponding phenylacetic acids in good yields.