491837-37-7

Basic information

• Product Name: (1S)-2-((S)-oxiranyl)-1-phenylethanol
• Synonyms: (1S)-2-((S)-oxiranyl)-1-phenylethanol
• CAS NO: 491837-37-7
• Molecular Weight: 164.204
• Mol File: 491837-37-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1S)-2-((S)-oxiranyl)-1-phenylethanol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S)-2-((S)-oxiranyl)-1-phenylethanol(491837-37-7)
• EPA Substance Registry System: (1S)-2-((S)-oxiranyl)-1-phenylethanol(491837-37-7)

Safety Data

• Hazardous Substances Data: 491837-37-7(Hazardous Substances Data)

Upstream product

• 77118-87-7 (S)-1-Phenyl-3-buten-1-ol 
• 6919-61-5 N-methoxy-N-methylbenzamide 
• 423763-77-3 (1R)-carbonic acid tert-butyl ester 1-phenylbut-3-enyl ester 
• 423763-78-4 (4S,6R)-4-iodomethyl-6-phenyl[1,3]dioxan-2-one 
• 423763-79-5 (1R,3S)-2-oxiranyl-1-phenyl-ethanol 
• 85551-57-1 (R)-1-Phenylbut-3-en-1-ol 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 6249-80-5 1-phenylbut-3-en-1-one 
• 20780-53-4 (R)-Styrene oxide 
• 491837-38-8 (1S,3S)-4-nitrobenzoic acid 2-oxiranyl-1-phenylethyl ester 

Downstream Products

• 491837-39-9 (1S,3S)-tert-butyldimethyl(2-oxiranyl-1-phenylethoxy)silane 
• 491837-47-9 (2'S,1S)-{1-[2-(tert-butyldimethylsilanoxy)-2-phenylethyl]-7-oxo-7-phenylhept-5-enyl}methylcarbamic acid tert-butyl ester 
• 491837-45-7 (5S,7S)-methanesulfonic acid 5-(tert-butoxycarbonylmethylamino)-7-(tert-butyldimethylsilanoxy)-7-phenylheptyl ester 
• 491837-44-6 (2'S,1S)-{1-[2-(tert-butyldimethylsilanoxy)-2-phenylethyl]-5-hydroxypentyl}methylcarbamic acid tert-butyl ester 
• 491837-43-5 (2'S,1S)-{1-[2-(tert-butyldimethylsilanoxy)-2-phenylethyl]pent-4-enyl}methylcarbamic acid tert-butyl ester 
• 491837-46-8 (2'S,1S)-{1-[2-(tert-butyldimethylsilanoxy)-2-phenylethyl]-5-oxopentyl}methylcarbamic acid tert-butyl ester 
• 491837-41-3 (2'S,1R)-methanesulfonic acid 1-[2-(tert-butyldimethylsilanoxy)-2-phenylethyl]pent-4-enyl ester 
• 491837-42-4 (2'S,1S)-{1-[2-(tert-butyldimethylsilanoxy)-2-phenylethyl]pent-4-enyl}methylamine 
• 491837-40-2 (1S,3R)-1-(tert-butyldimethylsilanoxy)-1-phenylhept-6-en-3-ol 
• 90-69-7 lobeline 
• 497-88-1 (-)-sedamine 

Relevant articles and documents

A facile synthetic route to (+)-allosedamine via hydrolytic kinetic resolution and olefin metathesis

A concise synthesis of (+)-allosedamine has been achieved using cobalt-catalyzed hydrolytic kinetic resolution (HKR) and ruthenium-catalyzed ring closing metathesis (RCM) as two key steps, in which HKR was used to introduce both stereogenic centers in the natural compound with a high degree of diastereomeric ratio and cyclization was carried out with the well developed RCM procedure.