492465-36-8

Basic information

• Product Name: (C₅H₅)Ru(C(CH₃)C(CH₂)3CC(CH₃)P(C₆H₁₁)3)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru(C(CH₃)C(CH₂)3CC(CH₃)P(C₆H₁₁)3)]PF₆
• Synonyms: (C₅H₅)Ru(C(CH₃)C(CH₂)3CC(CH₃)P(C₆H₁₁)3)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru(C(CH₃)C(CH₂)3CC(CH₃)P(C₆H₁₁)3)]PF₆
• CAS NO: 492465-36-8
• Molecular Weight: 711.757
• Mol File: 492465-36-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₅H₅)Ru(C(CH₃)C(CH₂)3CC(CH₃)P(C₆H₁₁)3)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru(C(CH₃)C(CH₂)3CC(CH₃)P(C₆H₁₁)3)]PF₆(CAS DataBase Reference)
• NIST Chemistry Reference: (C₅H₅)Ru(C(CH₃)C(CH₂)3CC(CH₃)P(C₆H₁₁)3)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru(C(CH₃)C(CH₂)3CC(CH₃)P(C₆H₁₁)3)]PF₆(492465-36-8)
• EPA Substance Registry System: (C₅H₅)Ru(C(CH₃)C(CH₂)3CC(CH₃)P(C₆H₁₁)3)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru(C(CH₃)C(CH₂)3CC(CH₃)P(C₆H₁₁)3)]PF₆(492465-36-8)

Safety Data

• Hazardous Substances Data: 492465-36-8(Hazardous Substances Data)

Upstream product

• 31699-35-1 2,7-nonadiyne 
• 247064-70-6 [(cyclopentadienyl)bis(acetonitrile)(tricyclohexylphosphine)ruthenium(II)] hexafluorophosphate 

Relevant articles and documents

Reactivity of a metallacyclopentatriene intermediate: metal-to-ligand-to-metal re-migration of a phosphine ligand versus a 1,2 hydrogen shift

The reaction of nona-2,7-diyne, deca-2,8-diyne and hex-1-yne with [RuCp(PR3)(MeCN)2]PF6 (R = Cy, Ph, Me) affords, depending on the structure of the alkyne and the substituent of the phosphine ligand, ruthenium metallacyclopentatriene, allyl carbene and/or butadienyl carbene complexes involving either metal-to-ligand-to-metal migration of the phosphine ligand with concomitant C-H activation or a facile 1,2 hydrogen shift.