49695-20-7

Basic information

• Product Name: (CO)3(1,2-bis(diphenylphosphino)ethane)MnCl
• CAS NO: 49695-20-7
• Molecular Weight: 572.846
• Mol File: 49695-20-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (CO)3(1,2-bis(diphenylphosphino)ethane)MnCl(CAS DataBase Reference)
• NIST Chemistry Reference: (CO)3(1,2-bis(diphenylphosphino)ethane)MnCl(49695-20-7)
• EPA Substance Registry System: (CO)3(1,2-bis(diphenylphosphino)ethane)MnCl(49695-20-7)

Safety Data

• Hazardous Substances Data: 49695-20-7(Hazardous Substances Data)

Upstream product

• 37583-89-4 (1,2-bis-diphenylphosphinoethane)tricarbonylmanganese 
• 364046-03-7 (CO)3(1,2-bis(diphenylphosphino)ethane)MnF 
• 7647-14-5 sodium chloride 
• 7647-01-0 hydrogenchloride 
• 133872-72-7 Mn(CO)3(1,2-bis(diphenylphosphino)ethane)(COOCH₃) 
• 57812-91-6 tricarbonyl(η(6)-chlorobenzene)manganese hexafluorophosphate 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 
• 133872-67-0 fac-(CO)3(1,2-bis(diphenylphosphino)ethane)Mn(OCH₃) 
• 100-07-2 4-methoxy-benzoyl chloride 
• 14100-30-2 pentacarbonylchloromanganese(I) 
• 56-23-5 tetrachloromethane 
• 17100-08-2 fac-tricarbonyl(1,2-bis(diphenylphosphino)ethane)hydridomanganese(I) 
• 201486-95-5 [Mn(CO)4(1,2-bis(diphenylphosphino)ethane)]Cl 
• 201486-94-4 fac-Mn(CO)3(1,2-bis(diphenylphosphino)ethane)(OCOOH) 

Downstream Products

• 145088-67-1 [Mn(CO)4(1,2-bis(diphenylphosphino)ethane)](BF₄) 
• 247939-32-8 fac-[Mn(CO)3(H₂O)(1,2-bis(diphenylphosphino)ethane)](BF₄)*water 
• 247939-39-5 fac-[Mn(CO)3(triphenylphosphino)(1,2-bis(diphenylphosphino)ethane)](BF₄) 

Relevant articles and documents

A novel dimanganese complex linked by an unusually strong hydrogen bond. X-ray structure of the hydrogen-bonded complex and ab initio calculations

In an attempt to prepare the fluoro complex (CO)3(dppe)MnF (3) by treating a CH2Cl2 solution of the aqua complex [(CO)3(dppe)Mn(OH2)]BF4 (1) with NaF(aq), we isolated instead, the dimanganese complex, [(CO)3(dppe)Mn(OH2)FMn(dppe)(CO)3]BF 4 (2). The two moieties, 1 and 3, are held together by an unusually strong O-HF hydrogen bond (OF=2.458(3) ?, HF=1.52 ?) between the aqua ligand on one manganese and the fluoro atom on the other manganese. Using as a simple model the interaction between +Li(H2O) and FLi, the hydrogen bonding distance O-HF was calculated to be; OF=2.443 ?. Authentic 3 was prepared in a homogeneous system using CH2Cl2-soluble [Et4N]F.

Conversion of a manganese-carbon-bonded complex to a manganese-oxygen-bonded complex, some reactions of manganese carbonato complexes

Stirring a solution of the manganese carboxylate, (dppe)(CO)3Mn-C(O)OCH3, 1, in dichloromethane saturated with water converts it to the bridging carbonato complex, (dppe)(CO)3Mn-OC(O)O-Mn(CO)3(dppe), 2. This multi-step conversion involves the in-situ transformation of a Mn-C bonded complex to a Mn-O bonded one. When 2 is stirred with HCl, it is converted quantitatively to the covalent chloride (dppe)(CO)3Mn-Cl, 11, with evolution of carbon dioxide. Similar HCl treatment of the manganese carboxylate 1 gives three compounds: the same covalent chloride, 11; the ionic chloride, [(dppe)(CO)4Mn] + Cl-, 12, and the hydride, (dppe)(CO)3Mn-H, 5. Reasonable schemes for these conversions are suggested. Heating the ionic chloride complex to its melting point converts it to the covalent chloride complex; the same transformation is accomplished by refluxing the ionic chloride in acetonitrile.

Reactions of ditertiary phosphines with η6-arenetricarbonylmanganese cations

Ditertiaryphosphines PPh2(CH2)nPPh2 (n = 1-3) react at room temperature with the η6-arenetricarbonylmanganese cations 6-XYC6H4)Mn(CO)3>+ (Ia, X = Y = H; Ib, X = Me, Y = H) by monocarbonyl substitution an formation of 6-XYC6H4)Mn(CO)2(η1-PPh2(CH2)nPPh2)>+.Prolonged refluxing results in metal-ring bond breaking and formation of cis- and trans-2-PPh2CH2PPh2)2>+ and trans-2-PPh2(CH2)2PPh2)2>+.Activation of a carbonyl group in 6-XYC6H4Mn(CO)2(η1-PPh2(CH2)nPPh2)>+ by TMNO gives the series of chelate complexes 6-XYC6H4Mn(CO)(η2-PPh2(CH2)nPPh2)>+ (n = 1 - 3).The X-ray structure of the chelate with n = 3 is reported.In the case of 6-XYC6H4)Mn(CO)3>+ (Ic, X = Cl, Y = H); Id, X = Cl, Y= Me), formation of fac-Mn(CO)3(η2-PPh2(CH2)nPPh2Cl (n = 1, 2) occurs, in a reaction analogous to that with monophosphines, see D.A.Brown, W.K.Glass and K.M.Kreddan, J.Organomet.Chem., 413 (1991) 223, but there was no evidence for ring adducts as intermediates.