497096-73-8

Basic information

• Product Name: Acetic acid (2S,3R,4R,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-(4-diphenylphosphanyl-benzoylamino)-tetrahydro-pyran-4-yl ester
• Synonyms: Acetic acid (2S,3R,4R,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-(4-diphenylphosphanyl-benzoylamino)-tetrahydro-pyran-4-yl ester
• CAS NO: 497096-73-8
• Molecular Weight: 635.607
• Mol File: 497096-73-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Acetic acid (2S,3R,4R,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-(4-diphenylphosphanyl-benzoylamino)-tetrahydro-pyran-4-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (2S,3R,4R,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-(4-diphenylphosphanyl-benzoylamino)-tetrahydro-pyran-4-yl ester(497096-73-8)
• EPA Substance Registry System: Acetic acid (2S,3R,4R,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-(4-diphenylphosphanyl-benzoylamino)-tetrahydro-pyran-4-yl ester(497096-73-8)

Safety Data

• Hazardous Substances Data: 497096-73-8(Hazardous Substances Data)

Upstream product

• 2129-31-9 4-diphenylphosphanobenzoic acid 
• 17460-45-6 tetra-acetyl glucosamine 

Relevant articles and documents

Glucosamine-based phosphines. Efficient ligands in the Suzuki cross-coupling reaction in water

Coupling of protected or non-protected D-glucosamine with o- or p-(diphenylphosphino)benzoic acid generates carbohydrate-substituted phosphines in quite good yields. The catalytic performance of these new neutral ligands is demonstrated in the Suzuki cross-coupling reaction. The polyhydroxy phosphines are more active than the peracetylated phosphines, and the process tolerates electron-rich as well as electron-poor substituents. Excellent turnovers are observed, and the catalyst can be recycled.