49751-95-3Relevant articles and documents
Rhodium Catalysts with a Chiral Cyclopentadienyl Ligand Derived from Natural R-Myrtenal
Kolos, Andrey V.,Nelyubina, Yulia V.,Perekalin, Dmitry S.,Pototskiy, Roman A.
, p. 6019 - 6025 (2020)
A new chiral cyclopentadiene CpmyrH was synthesized from the natural terpene (R)-myrtenal in 5 steps and about 40 % total yield. The key step was the reaction of vinyl-dibromocyclopropane derivative with MeLi which provided the diene Cpmyr
