49815-58-9Relevant articles and documents
Synthesis of chlorins and bacteriochlorins from cycloaddition reactions with porphyrins
Cavaleiro, José A. S.,Monteiro, Carlos J. P.,Moura, Nuno M. M.,P. M. S. Neves, M. Gra?a,Tomé, Augusto C.
, (2022/02/10)
Chlorins and bacteriochlorins are reduced porphyrin-type derivatives displaying characteristic structural, physical, and chemical features. Such features make chlorins and bacteriochlorins key “players” in several fields, and specifically in medicine as p
METHOD OF RAPID METHYLATION OF ALKENE COMPOUND AND KIT FOR PET TRACER PREPARATION USING THE SAME
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Page/Page column 5; 6, (2008/12/07)
To provide a method of rapid methylation of alkenes, which is applicable to the preparation of a PET tracer and which enables alkenes to be methylated through cross coupling between SP2 (alkenyl) and SP3 (alkyl) carbon atoms rapidly and in a high yield. Methyl iodide and an alkenyltrialkylstannane are subjected to cross coupling in an aprotic polar solvent in the presence of a palladium complex having a valence of 0, a phosphine ligand, a cuprous halide, and a carbonate and/or alkali metal fluoride.