49860-18-6

Basic information

• Product Name: trichloroborane-NH₃ adduct monomer
• Synonyms: trichloroborane-NH₃ adduct monomer
• CAS NO: 49860-18-6
• Molecular Weight: 134.201
• Mol File: 49860-18-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trichloroborane-NH₃ adduct monomer(CAS DataBase Reference)
• NIST Chemistry Reference: trichloroborane-NH₃ adduct monomer(49860-18-6)
• EPA Substance Registry System: trichloroborane-NH₃ adduct monomer(49860-18-6)

Safety Data

• Hazardous Substances Data: 49860-18-6(Hazardous Substances Data)

Upstream product

• 10294-34-5 boron trichloride 

Downstream Products

• 933-18-6 B,B',B''-trichloroborazine 

Relevant articles and documents

Preparation, Spectra and X-Ray Structure of an Archetypal Coordination Compound and its Thermolysis

Crystalline 1 is obtained in low yield from Cl and BCl3 in toluene, with trichloroborazine (BClNH)3 2 as the principal product; detailed NMR spectroscopic data on 1 in CDCl3 are consistent with the X-ray structure, which shows intermolecular hydrogen bonding with four molecules in the unit cell av 2.76(3) Angstroem>, B-N 1.579(4), (B-Cl)av 1.837(4) and (N-H)av 0.86(5) Angstroem, with the boron and nitrogen environments approximately tetrahedral; thermolysis of 1 yields 2 and a TGA experiment shows that at 450 deg C boron nitride is the ultimate product.