5014-43-7

Basic information

• Product Name: C₆H₁₂ClNO
• Synonyms: C₆H₁₂ClNO
• CAS NO: 5014-43-7
• Molecular Weight: 149.62
• Mol File: 5014-43-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₆H₁₂ClNO(CAS DataBase Reference)
• NIST Chemistry Reference: C₆H₁₂ClNO(5014-43-7)
• EPA Substance Registry System: C₆H₁₂ClNO(5014-43-7)

Safety Data

• Hazardous Substances Data: 5014-43-7(Hazardous Substances Data)

Upstream product

• 6830-83-7 N-methyl-pivalamide 

Relevant articles and documents

The Structure of Amidyl Radicals. Evidence for the ?-Electronic Ground State and for Twist about the Acyl-Nitrogen Bond by Electron Paramagnetic Resonance Spectroscopy

The EPR spectroscopic parameters for a number of acyclic N-alkylcarboxamidyls, RC(O)R', have been measured over a wide range of temperatures.The results can only be interpreted in terms of ?-electronic configuration in which the unpaired electron resides mainly in an N 2p orbital perpendicular to the RNC plane.Measurements of the 13C hyperfine splittings (hfs) for some RC(O)(13)CH3 demonstrate that the O and 13C atoms lie in or near the RNC plane except when R ist tert-butyl, in which case steric forces twist these atoms out of this plane by 20 deg or more.There is less conjugative delocalization of the unpaired electron from N to O in the Me3CC(O)R' radicals because they are twisted and hence these radicals have a larger N hfs and a smaller g value than amidyls which have R = primary or secondary alkyl.The first cyclic amidyl, 5,5-dimethyl-2-oxopyrrolidin-1-yl, has been detected.This radical has a smaller N hfs (11.2 G) and a higher g value (2.0063) than the acyclic radicals.