5016-08-0Relevant articles and documents
Synthesis, physicochemical and optical characterization of novel fluorescing complex: O-phenylenediamine-benzoin
Dwivedi,Kant, Shiva,Rai,Rai
, p. 1255 - 1263 (2011)
The complex of o-phenylenediamine (o-PDA) and benzoin (BN) was synthesized adopting solid state reaction by mixing of their melt together followed by chilling. The phase diagram study shows the formation of a complex in 1:1 molar ratio with congruent melt
Synthesis and investigation of mass spectra of some nitrogen heterocycles
Hasanen,Ibrahim
experimental part, p. 337 - 351 (2009/09/06)
2,3-DIPHENYL-1, 2-dihydro-quinoxaline (2), 2, 3-diphenyl-quinoxaline (3) and 2, 3-diphenyl-1, 2, 3, 4-tetrahydroquinoxaline (4) were prepared via the reaction of benzoin with o-phenylene diamine under different reaction conditions. Acylation of 2 and 4 with acetic anhydride yielded the corresponding N-acetyl (5) and N, N-1, 4-diacetyl derivative (7), respectively. Bromination of 2 with bromine gave the corresponding 6, 7-dibromo-2,3- diphenyl-quinoxaline (6). 2, 3, 5, 6-tetraphenylpyrazine (8) and 1-(benzylidene) amino-4, 5-diphenyl-1,5-dihydro-imidazoldine-2-thione (9) were synthesized by treatment of benzoin (1) with thiourea and benzaldehyde-thiosemicarbazone. The electron impact mass spectra of both of the above series of compounds have also been recorded and their fragmentation pattern is discussed.
Titanium(III) Chloride and Electrochemical Reduction of Pyrazine, Quinoxaline and Triazine Derivatives and of their Salts
Armand, J.,Chekir, K.,Pinson, J.
, p. 1237 - 1240 (2007/10/02)
The reduction of pyrazine, quinoxaline and triazine derivatives by titanium(III) chloride leads to di- or tetrahydrogenated compounds.High yields of tetrahydro compounds are also obtained through the reduction of quinoxalinium salts.These results are comp