501909-58-6

Basic information

• Product Name: [Ir(III)(η(3)-CH2CHCHPh)(Cl)2(η(4)-1,5-COD)]
• CAS NO: 501909-58-6
• Molecular Weight: 488.48
• Mol File: 501909-58-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ir(III)(η(3)-CH2CHCHPh)(Cl)2(η(4)-1,5-COD)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ir(III)(η(3)-CH2CHCHPh)(Cl)2(η(4)-1,5-COD)](501909-58-6)
• EPA Substance Registry System: [Ir(III)(η(3)-CH2CHCHPh)(Cl)2(η(4)-1,5-COD)](501909-58-6)

Safety Data

• Hazardous Substances Data: 501909-58-6(Hazardous Substances Data)

Upstream product

• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 12112-67-3 bis(1,5-cyclooctadiene)diiridium(I) dichloride 

Relevant articles and documents

Iridium-catalysed allylic substitution: Stereochemical aspects and isolation of IrIII complexes related to the catalytic cycle

Ir-catalysed allylic alkylations of enantiomerically enriched monosubstituted allylic acetates proceed with up to 87% retention of configuration using P(OPh)3 as ligand. High retention enantioselectivity of up to 86% ee in asymmetric allylic alkylations of achiral or racemic substrates is achieved with monodentate phosphorus amidites as ligands. Lithium N-tosylbenzylamide was identified as a suitable nucleophile for allylic aminations. Of particular importance is the use of lithium chloride as an additive, generally leading to increased enantioselectivities. Two (π-allyl)IrIII complexes were characterised by X-ray crystal structure analysis and spectroscopic data.