50289-98-0

Basic information

• Product Name: diacetoxytriphenylarsorane
• CAS NO: 50289-98-0
• Molecular Weight: 424.328
• Mol File: 50289-98-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: diacetoxytriphenylarsorane(CAS DataBase Reference)
• NIST Chemistry Reference: diacetoxytriphenylarsorane(50289-98-0)
• EPA Substance Registry System: diacetoxytriphenylarsorane(50289-98-0)

Safety Data

• Hazardous Substances Data: 50289-98-0(Hazardous Substances Data)

Upstream product

• 2526-65-0 triphenylarsenic dichloride 
• 64-19-7 acetic acid 
• 33708-54-2 triphenylarsenazophenyl 
• 603-32-7 triphenyl-arsane 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 110788-31-3 N-(p-bromophenyl)triphenylarsine imide 

Downstream Products

• 74722-09-1 N-(di-t-butylphosphinoyl)triphenylarsoranylideneamine 
• 74722-22-8 N-(di-isopropylphosphinoyl)triphenylarsoranylideneamine 
• 74722-21-7 N-(2,2,t-3,4,4-pentamethylphosphetan-r-1-yl)triphenylarsoranylideneamine P-oxide 

Relevant articles and documents

Reactions of PhIX2I(iii) oxidants with heavy triphenyl pnictines

The reactions of [PhI(pyridine)2]2+, PhI(OAc)2and PhI(OTf)(OAc) with Ph3As, Ph3Sb and Ph3Bi are described. The reactions of [PhI(pyridine)2]2+with Ph3Sb and Ph3Bi afford dicationic Pn(v) complexes ligated by pyridine in one step. These were previously reported by Burford in multi-step syntheses. Reactions with PhI(OAc)2, which were already known for Sb and Bi giving Pn(v) diacetates, were confirmed to give the same type of compound for As. Reactions with PhI(OAc)(OTf) were less selective, resulting in the isolation of iodonium cations [Ph-I-Ph]+for As and Bi, while Ph3Sb gave an oxobridged di-antimony species characteristic of the decomposition of a high valent triflate bound species.