50300-19-1

Basic information

• Product Name: Silane, [(1Z)-1-heptenyloxy]trimethyl-
• CAS NO: 50300-19-1
• Molecular Formula: C10H22OSi
• Molecular Weight: 186.37
• Mol File: 50300-19-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, [(1Z)-1-heptenyloxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(1Z)-1-heptenyloxy]trimethyl-(50300-19-1)
• EPA Substance Registry System: Silane, [(1Z)-1-heptenyloxy]trimethyl-(50300-19-1)

Safety Data

• Hazardous Substances Data: 50300-19-1(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 3739-64-8 allyl n-butyl ether 

Downstream Products

• 422321-30-0 tert-Butyl-((1S,2S)-2-dimethoxymethyl-1-phenyl-heptyloxy)-dimethyl-silane 
• 422321-09-3 (1S,2S)-2-Dimethoxymethyl-1-phenyl-heptan-1-ol 
• 56149-68-9 (3-anilino-2-pentyl-2-propenylidene)anilinium chloride 

Relevant articles and documents

THE WITTIG REARRANGEMENT AS A PRACTICAL METHOD FOR ALDEHYDE SYNTHESIS

If the rearrangement of metalated allyl ethers 2 (or 4) is accomplished in the presence of potassium tert-butoxide, primary alkyl groups preferentially migrate to the unsubstituted allylic terminus (γ-position).Enolates 7 and 1-vinylalcoholates 6 (by alkyl migration to the α-position, adjacent to the oxygen atom) are produced in an approximate ratio of 9 : 1.Because of the endo-configuration of their organometallic precursors, the enolates exclusively emerge in the (Z)-configuration as shown by trapping with chlorotrimethylsilane and isolation of the resulting O-silyl (Z)-enethers.Hydrolysis of the latter affords the corresponding aldehydes with good yields. -The rearrangement is mechanistically still obscure.A concerted process as the main reaction mode is unlikely.The intermediacy of zwitterionic metallomers 18 and solvent caged radical pairs 17 is tentatively suggested.