503454-05-5

Basic information

• Product Name: ([(n-BuSn)3(μ3-O)(OC6H5)3]2[HPO3]4)
• CAS NO: 503454-05-5
• Molecular Weight: 1965.5
• Mol File: 503454-05-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ([(n-BuSn)3(μ3-O)(OC6H5)3]2[HPO3]4)(CAS DataBase Reference)
• NIST Chemistry Reference: ([(n-BuSn)3(μ3-O)(OC6H5)3]2[HPO3]4)(503454-05-5)
• EPA Substance Registry System: ([(n-BuSn)3(μ3-O)(OC6H5)3]2[HPO3]4)(503454-05-5)

Safety Data

• Hazardous Substances Data: 503454-05-5(Hazardous Substances Data)

Upstream product

• 4712-55-4 diphenyl hydrogen phosphite 
• 2273-43-0 n-butylstannoic acid 
• 13598-36-2 phosphonic Acid 
• 108-95-2 phenol 

Relevant articles and documents

A new structural form of tin in a double O-capped cluster

Two new cyanorhenate complexes of potential utility in constructing magnetic and photomagnetic materials are reported. Reaction of (Bu4N)CN with [ReCl6]2- in acetonitrile affords yellow (Bu4N)3[Re(CN)7] (1), featuring the pentagonal bipyramidal complex [Re(CN)7]3-. The spectral and magnetic properties of 1 indicate that the complex has an S = 1/2 ground state with considerable anisotropy in the g tensor. In aqueous solution, 1 reacts with Mn2+ ions to generate the three-dimensional cyano-bridged solid [fac-Mn(H2O)3][cis-Mn(H2O)2][Re(CN)7]·3H2O (2) containing diamagnetic [Re(CN)7]4-. Addition of KIO4 to the reaction solution, originally intended to prevent reduction of the rhenium during solid formation, instead yields white (Bu4N)3[Re(CN)8] (3). As crystallized in K3[Re(CN)8]·2MeCN (4·2MeCN), the diamagnetic [Re(CN)8]3- complex adopts a nearly perfect square antiprismatic coordination geometry. In solution, this species behaves analogously to the isoelectronic [M(CN)8]4- (M = Mo, W) complexes, apparently converting to a dodecahedral geometry and photooxidizing under UV radiation to give paramagnetic [Re(CN)8]2-. Copyright