503590-21-4

Basic information

• Product Name: (R)-4-Benzyl-3-[(triisopropylsilanyl)-ethynyl]-oxazolidin-2-one
• Synonyms: (R)-4-Benzyl-3-[(triisopropylsilanyl)-ethynyl]-oxazolidin-2-one
• CAS NO: 503590-21-4
• Molecular Weight: 357.568
• Mol File: 503590-21-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-4-Benzyl-3-[(triisopropylsilanyl)-ethynyl]-oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-4-Benzyl-3-[(triisopropylsilanyl)-ethynyl]-oxazolidin-2-one(503590-21-4)
• EPA Substance Registry System: (R)-4-Benzyl-3-[(triisopropylsilanyl)-ethynyl]-oxazolidin-2-one(503590-21-4)

Safety Data

• Hazardous Substances Data: 503590-21-4(Hazardous Substances Data)

Upstream product

• 40217-17-2 (R)-4-(phenylmethyl)-2-oxazolidinone 
• 111409-79-1 1-bromo-2-(triisopropylsilyl)acetylene 

Downstream Products

• 503590-22-5 (R)-4-benzyl-3-ethynyloxazolidin-2-one 

Relevant articles and documents

Highly substituted 2-amido-furans from rh(ll)-catalyzed cyclopropenations of ynamides

Rh(II)-catalyzed cyclopropenations of ynamides are described. Although an actual amido-cyclopropene intermediate may not be involved, these reactions provide a facile entry to highly substituted 2-amido-furans, thereby formerly constituting a [3 + 2] cycloaddition. An application of these de novo 2-amido-furans In N-tethered intramolecular [4 + 2] cycloadditions is also illustrated, leading to dihydroindoles and tetrahydroqulnolines