50404-36-9

Basic information

• Product Name: thiofenchone S-oxide
• Synonyms: thiofenchone S-oxide
• CAS NO: 50404-36-9
• Molecular Weight: 184.302
• Mol File: 50404-36-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: thiofenchone S-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: thiofenchone S-oxide(50404-36-9)
• EPA Substance Registry System: thiofenchone S-oxide(50404-36-9)

Safety Data

• Hazardous Substances Data: 50404-36-9(Hazardous Substances Data)

Upstream product

• 875-06-9 1,3,3-trimethyl-bicyclo[2.2.1]heptane-2-thione 

Relevant articles and documents

Photochemical Oxidation of Thioketones: Steric and Electronic Aspects

Oxidation of diaryl, aryl alkyl, and dialkyl thioketones by singlet oxygen generated via self-sensitization and other independent methods yielded the corresponding ketone and sulfine in varying amounts.A zwitterionic/diradical intermediate arising out of the primary interaction of singlet oxygen with the thiocarbonyl chromophore is believed to be the common intermediate for the ketone and sulfine.While closure of the zwitterion/diradical to give 1,2,3-dioxathietane would lead to the ketone, competing oxygen elimination is believed to lead to the sulfine.This partitioning is governed by steric and electronic factors operating on the zwitterionic/diradical intermediate.