50434-32-7

Basic information

• Product Name: Benzene, 1,1'-(2-chloro-1,3-propanediyl)bis-
• CAS NO: 50434-32-7
• Molecular Formula: C15H15Cl
• Molecular Weight: 230.737
• Mol File: 50434-32-7.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(2-chloro-1,3-propanediyl)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(2-chloro-1,3-propanediyl)bis-(50434-32-7)
• EPA Substance Registry System: Benzene, 1,1'-(2-chloro-1,3-propanediyl)bis-(50434-32-7)

Safety Data

• Hazardous Substances Data: 50434-32-7(Hazardous Substances Data)

Upstream product

• 49802-75-7 2-benzyl-3-phenyl-propionyl chloride 
• 618-68-8 2-benzyl-3-phenylpropanoic acid 
• 300-57-2 allylbenzene 
• 62-53-3 aniline 
• 102-04-5 1,3-Diphenylpropanone 
• 5381-92-0 1,3-diphenylpropan-2-ol 
• 32315-10-9 bis(trichloromethyl) carbonate 
• 121-44-8 triethylamine 
• 960-16-7 tributylphenylstannane 
• 888021-85-0 2-(1-benzyl-2-phenyl-ethoxysulfonyl)-benzoic acid 2-(2-methoxy-ethoxy)-ethyl ester 
• 118334-81-9 2-Benzyl-3-phenyl-propionic acid 1,3-dioxo-1,3-dihydro-isoindol-2-yl ester 

Downstream Products

• 53097-56-6 2-benzyl-3-phenylpropionitrile 
• 3412-44-0 (1E)-1,3-diphenylpropene 

Relevant articles and documents

Preparation method of alkyl nitrile compound

The invention discloses a preparation method of an alkyl nitrile compound shown as formula I. The preparation method comprises the following step: in a solvent, in the presence of an additive and a catalyst, Zn (CN) 2 and an alkyl halide shown as formula II are subjected to a coupling reaction as shown in the specification to obtain the alkyl nitrile compound as shown in the formula I, wherein theadditive comprises an alkali, the catalyst comprises a nickel compound and a phosphine ligand; the nickel compound is one or more of zero-valent nickel, monovalent nickel salt and divalent nickel salt; when the nickel compound contains zero-valent nickel or divalent nickel salt, the catalyst further comprises a reducing agent. According to the preparation method disclosed by the invention, cyanation of an alkyl halide can be simply, conveniently and efficiently realized by using a cheap catalytic system, and the preparation method also has good functional group compatibility and substrate universality.

Chlorination of aliphatic primary alcohols via triphosgene-triethylamine activation

Activation of primary aliphatic alcohols with triphosgene and triethylamine mixtures afforded either alkyl chloride or diethylcarbamate products, and the switch in selectivity appeared to be driven by sterics. The reaction conditions to achieve this highly useful transformation were unexceptionally mild and readily tolerated by a wide range of sensitive functionalities.

Oxidatively intercepting heck intermediates: Pd-catalyzed 1,2- and 1,1-arylhalogenation of alkenes

This communication describes the development of two Pd-catalyzed reactions for the arylchlorination of diverse α-olefins by oxidatively intercepting Heck intermediates. Depending on the nature of the oxidant and the reaction conditions, these transformati