50460-72-5Relevant articles and documents
Synthesis and stereochemistry of β-aryl-β-haloacroleins: Useful intermediates for the preparation of (Z) and (E)-2-en-4-ynecarbaldehydes and for the synthesis of rubrolides
Prim, Damien,Fuss, Alexia,Kirsch, Gilbert,Silva, Artur M. S.
, p. 1175 - 1180 (2007/10/03)
The synthesis of α-substituted β-aryl-β-haloacroleins by two different pathways is presented. The determination of their stereochemistry by NOE experiments is reported for the first time. Furthermore, we describe the preparation of 2-en-4-ynecarbaldehydes