5048-29-3

Basic information

• Product Name: 7-OCTENENITRILE
• Synonyms: 7-OCTENENITRILE
• CAS NO: 5048-29-3
• Molecular Formula: C₈H₁₃N
• Molecular Weight: 123.2
• Mol File: 5048-29-3.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 214.571°C at 760 mmHg
• Flash Point: 89.799°C
• Appearance: /
• Density: 0.826g/cm³
• Vapor Pressure: 0.155mmHg at 25°C
• Refractive Index: 1.433
• CAS DataBase Reference: 7-OCTENENITRILE(CAS DataBase Reference)
• NIST Chemistry Reference: 7-OCTENENITRILE(5048-29-3)
• EPA Substance Registry System: 7-OCTENENITRILE(5048-29-3)

Safety Data

• Hazardous Substances Data: 5048-29-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C8H13N/c1-2-3-4-5-6-7-8-9/h2H,1,3-7H2

Upstream product

• 935-30-8 2-azacyclononanone 
• 1074-51-7 cyclooctanone oxime 
• 36291-53-9 1-nitro-1-cycloheptene 
• 13170-43-9 (trimethylsilyl)methylmagnesium chloride 
• 129266-41-7 2-Tributylstannanylmethyl-cycloheptanone oxime 
• 152840-90-9 (hex-5-enyl)propanedinitril 
• 773837-37-9 sodium cyanide 
• 4117-09-3 7-bromo-hept-1-ene 
• 62179-18-4 2,7-octadiene-1-ol 
• 21573-31-9 oct-7-enal 

Downstream Products

• 74-85-1 ethene 
• 21573-31-9 oct-7-enal 

Relevant articles and documents

Novel Double Functional Group Transformation: 'One-flask' Conversion of 1-Nitrocycloalkenes to Terminally Unsaturated Nitriles

A new method has been developed for the conversion of 1-nitrocycloalkenes to terminally unsaturated nitriles in one flask by use of Me3SiCH2MgCl (1.8 equiv.) and PCl3 (2.5 equiv.) in tetrahydrofuran.

Combination of RCM and the Pauson-Khand reaction: One-step synthesis of tricyclic structures

The combination of ring-closing metathesis (RCM) followed by an intramolecular Pauson-Khand reaction gives direct entry to tricyclic compounds. The RCM was carried out on a hexacarbonylcobalt-complexed alkyne, this complex acting as a protecting group against enyne metathesis. The procedure was studied for dienynes containing heteroatoms and allows the building of [6,5,5] and [7,5,5] tricyclic systems. The feasibility of the process depends strongly on the nature of the substrate. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.

Tin-directed baeyer-villiger and beckman fragmentations

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