50585-29-0 Usage
Description
1,8-Bis(chloromethyl)naphthalene is an organic compound characterized by the presence of two chloromethyl groups attached to a naphthalene molecule. This chemical structure endows it with unique properties that make it suitable for various applications, particularly in the synthesis of other compounds.
Uses
Used in Chemical Synthesis Industry:
1,8-Bis(chloromethyl)naphthalene is used as a precursor in the synthesis of various organic compounds for different purposes. Its chloromethyl groups can be easily replaced or modified, making it a versatile building block in organic chemistry.
Specifically, 1,8-Bis(chloromethyl)naphthalene is used as a starting material for the production of acenapthene through a process called laser flash photolysis. This technique involves the use of a laser to rapidly break chemical bonds, allowing for the formation of new compounds, such as acenapthene, which has its own set of applications and properties.
Synthesis Reference(s)
Journal of the American Chemical Society, 78, p. 653, 1956 DOI: 10.1021/ja01584a036
Check Digit Verification of cas no
The CAS Registry Mumber 50585-29-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,0,5,8 and 5 respectively; the second part has 2 digits, 2 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 50585-29:
(7*5)+(6*0)+(5*5)+(4*8)+(3*5)+(2*2)+(1*9)=120
120 % 10 = 0
So 50585-29-0 is a valid CAS Registry Number.
50585-29-0Relevant articles and documents
Stereospecific Synthesis of 2,3-Dihydro-2-metallaphenalenes, meso- , via an Unstable Dilithium Reagent, 2> (tmeda = tetramethylethylenediamine), which is converted into the Complex containing a Silicon Heterocycl...
Papasergio, Rocco I.,Raston, Colin L.
, p. 1023 - 1025 (1982)
In situ Grignard reactions of 1,8-(ClCH2)2C10H6 have yielded 2,3-dihydro-2,2-dimethyl-2-silaphenalene, which can be selectively monolithiated at the 1-position, and 1,8-(Me3SiCH2)2C10H6, a compound readily dilithiated and subsequently converted into the zirconium and hafnium metallacycles, meso-; the dilithium complex is converted into the complex containing a silicon heterocycle dicarbanion and characterized as the substituted silaphenalene, the same product as the ClSiMe3 adduct of mono-lithiated silaphenalene.
Mild and efficient synthesis of 1,8-naphthalide and 1,8- naphthalenedimethanol
Luo, Huan,Zeng, Qingle,Liu, Zhongrong,Wei, Yongzhi,Li, Bogang,Wang, Fengpeng
, p. 2269 - 2275 (2007/10/03)
Mild and efficient procedures have been developed for synthesis of 1,8-naphthalide and 1,8-naphthalenedimethanol. In an ice-water bath, 1,8-naphthalide was prepared from 1,8-naphthlic anhydride using LiAlH 4 as reducing agent. 1,8-Naphthalenedi
