50605-03-3

Basic information

• Product Name: .beta.-D-Glucofuranoside, methyl 2-(acetylamino)-2-deoxy-5,6-O-(1-methylethylidene)-
• Synonyms: .beta.-D-Glucofuranoside, methyl 2-(acetylamino)-2-deoxy-5,6-O-(1-methylethylidene)-
• CAS NO: 50605-03-3
• Molecular Formula: C12H21NO6
• Molecular Weight: 275.3
• Mol File: 50605-03-3.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: .beta.-D-Glucofuranoside, methyl 2-(acetylamino)-2-deoxy-5,6-O-(1-methylethylidene)-(CAS DataBase Reference)
• NIST Chemistry Reference: .beta.-D-Glucofuranoside, methyl 2-(acetylamino)-2-deoxy-5,6-O-(1-methylethylidene)-(50605-03-3)
• EPA Substance Registry System: .beta.-D-Glucofuranoside, methyl 2-(acetylamino)-2-deoxy-5,6-O-(1-methylethylidene)-(50605-03-3)

Safety Data

• Hazardous Substances Data: 50605-03-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 117177-19-2 2-methyl-(1,2-dideoxy-5,6-O-isopropylidene-α-D-glucofurano)-<2,1-d>-2-oxazoline 
• 7512-17-6 N-Acetyl-D-glucosamine 
• 77-76-9 2,2-dimethoxy-propane 

Downstream Products

• 5517-54-4 methyl 2-acetamido-2-deoxy-β-D-glucofuranoside 
• 105265-96-1 2-acetamido-1,2-dideoxynojirimycin 
• 153373-83-2 N-((1R,2R,3S)-1-Formyl-2,3,5-trihydroxy-4-oxo-pentyl)-acetamide 
• 153373-82-1 methyl 2-acetamido-2-deoxy-β-D-xylo-hexofuranosid-5-ulose 
• 153373-85-4 methyl (methyl 2-acetamido-2-deoxy-β-D-glucofuranosid)uronate 
• 153373-84-3 methyl 2-acetamido-2-deoxy-β-D-glucofuranosidurono-6,3-lactone 

Relevant articles and documents

Facile approach to 2-acetamido-2-deoxy-β-D-glucopyranosides via a furanosyl oxazoline

(Chemical Equation Presented) A concise and convenient route that may be easily scaled is reported for the preparation of unprotected β-glucopyranosides of N-acetyl-D-glucosamine. Reaction of a wide variety of alcohols with a reactive, readily prepared furanosyl oxazoline under acidic conditions affords the corresponding β-D-glucopyranosides in good to high yields. Primary alcohols gave only β-D-glucopyranosides. A mechanism is proposed for this transformation.

A SIMPLE PREPARATION OF 2-(ACYLAMINO)-2-DEOXY-3,4:5,6-DI-O-ISOPROPYLIDENE-aldehydo-D-GLUCOSE DIMETHYL AND DIBENZYL ACETAL

When treated with a large excess of 2,2-dimethoxypropane or 2,2-dibenzyloxypropane in 1,4-dioxane solution in the presence of p-toluenesulfonic acid, 2-acetamido-2-deoxy-D-glucose and 2-(benzyloxycarbonylamino)-2-deoxy-D-glucose yield the corresponding 3,4:5,6-di-O-isopropylidene-aldehydo-D-glucose dimethyl or dibenzyl acetal in good yield.