508225-73-8

Basic information

• Product Name: (R)-N-(tert-butanesulfinyl)-N-(3-phenylpropyliden)amine
• Synonyms: (R)-N-(tert-butanesulfinyl)-N-(3-phenylpropyliden)amine
• CAS NO: 508225-73-8
• Molecular Weight: 237.366
• Mol File: 508225-73-8.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: (R)-N-(tert-butanesulfinyl)-N-(3-phenylpropyliden)amine(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-N-(tert-butanesulfinyl)-N-(3-phenylpropyliden)amine(508225-73-8)
• EPA Substance Registry System: (R)-N-(tert-butanesulfinyl)-N-(3-phenylpropyliden)amine(508225-73-8)

Safety Data

• Hazardous Substances Data: 508225-73-8(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 107-18-6 allyl alcohol 
• 196929-78-9 (R)-2-methylpropane-2-sulfinamide 
• 104-53-0 3-phenyl-propionaldehyde 

Downstream Products

• 1106778-15-7 C₁₅H₂₅NOS 
• 1106778-17-9 C₁₅H₂₅NOS 
• 1133832-00-4 (R(S))-N-((S,E)-1-phenyloctoct-4-en-3-yl)-2-methylpropanesulfinamide 
• 1232683-15-6 (2S,R(S))-N-(tert-butylsulfinyl)-1-[2-(2-hydroxyethyl)phenyl]-4-phenylbutan-2-amine 
• 1412429-46-9 dimethyl [(1R)-1-{[(R)-(tert-butyl)sulfinyl]amino}-3-phenylpropyl]propanedioate 
• 1412429-47-0 dimethyl [(1S)-1-{[(R)-(tert-butyl)sulfinyl]amino}-3-phenylpropyl]propanedioate 

Relevant articles and documents

Stereoselective Synthesis of Tetrahydroisoquinolines from Chiral 4-Azaocta-1,7-diynes and 4-Azaocta-1,7-enynes

The N-propargylation of enantioenriched homopropargylic amine derivatives 3 proceeds in high yields under basic conditions. The resulting 4-azaocta-1,7-dynes 5 were transformed into 1,2,3,4-tetrahydrosioquinolines 7 bearing substituents at 3-, 6- and 7-positions, upon reaction with symmetrical alkynes, through a [2+2+2] cyclotrimerization promoted by Wilkinson catalyst. Ruthenium-catalyzed ring closing metathesis of azaocta-1,7-enynes 9a and 15a gave 1,3-dienes 10a and 16a, respectively, in high yields. Tetrahydroisoquinolines 12a and 18a, with a substitution pattern in the aromatic ring different to that of compounds 7, were prepared by a [4+2] cycloaddition of dimethyl acetylenedicarboxylate with dienes 10a and 16a, respectively.

First sonochemical, simple and solvent-free synthesis of chiral tert-butanesulfinimines using silica supported p-toluenesulfonic acid

A solvent-free, versatile procedure has been developed for the effective synthesis of tert-butanesulfinylimines of a variety of aldehydes using chiral tert-butanesulfinamides under green, sonochemical conditions. This method utilizes silica supported p-to

Multifunctional 1,3-diphenylguanidine for the carboxylative cyclization of homopropargyl amines with CO2 under ambient temperature and pressure

Herein, we report that 1,3-diphenylguanidine (DPG) could be utilized for the carboxylative cyclization of homopropargyl amines with CO2 under ambient temperature and pressure, in combination with AgSbF6, which enabled the synthesis o