50868-76-3

Basic information

• Product Name: Acetamide, N-(2-methoxy-6-methylphenyl)-
• Synonyms: 2-Acetamino-3-methoxy-toluol;2-acetamido-3-methoxytoluene
• CAS NO: 50868-76-3
• Molecular Formula: C10H13NO2
• Molecular Weight: 179.219
• Mol File: 50868-76-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Acetamide, N-(2-methoxy-6-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, N-(2-methoxy-6-methylphenyl)-(50868-76-3)
• EPA Substance Registry System: Acetamide, N-(2-methoxy-6-methylphenyl)-(50868-76-3)

Safety Data

• Hazardous Substances Data: 50868-76-3(Hazardous Substances Data)

Upstream product

• 77774-35-7 N-(2-hydroxy-6-methylphenyl)acetamide 
• 77-78-1 dimethyl sulfate 
• 50868-73-0 2-methoxy-6-methylbenzeneamine 
• 5345-42-6 1-methoxy-3-methyl-2-nitro-benzene 
• 108-24-7 acetic anhydride 
• 4920-77-8 3-methyl-2-nitrophenol 
• 861304-53-2 6-methyl-4-methoxy-1,3-benzenedisulfonyl chloride 
• 861304-52-1 5-methoxy-6-nitro-toluene-2,4-disulfonyl chloride 
• 100-84-5 1-methoxy-3-methyl-benzene 
• 2835-97-4 2-amino-3-methylphenol 
• 93-26-5 2-methoxyacetanilide 
• 75-36-5 acetyl chloride 

Downstream Products

• 68701-23-5 2-amino-3-methoxybenzoic acid hydrochloride 
• 35214-99-4 8-methoxydeoxyvasicinone 
• 1266338-97-9 N-(2-methoxy-6-methyl-4-(N-(phenylsulfonyl)phenylsufonamido)phenyl)acetamide 
• 73568-28-2 2-chloro-8-methoxyquinoline-3-carbaldehyde 
• 81382-46-9 7-hydroxy-1H-indazole 
• 133841-05-1 7-methoxy-1H-indazole 

Relevant articles and documents

Synthesis of indenoquinolinone through aryne-mediated Pd(II)-catalysed remote C–H activation

Abstract: [Figure not available: see fulltext.]Indenoquinolinones have been synthesized from 2-haloquinoline-3-carbaldehyde through Pd-mediated simultaneous C–H (aldehyde) and C–X bond activation. DFT studies were performed to investigate the mechanistic pathway, and in situ UV–Vis studies indicate the presence of Pd(II) intermediate species. Aryne ligated Pd complex is actual intermediate in these reactions. Ligation of reactive aryne to Pd reduces probability of side reactions. Graphic abstract: [Figure not available: see fulltext.]

Palladium-catalyzed C-H aminations of anilides with N - fluorobenzenesulfonimide

The first amide-directed, palladium-catalyzed, intermolecular, highly selective C-H aminations with the non-nitrene-based nitrogen source N-fluorobenzenesulfonimide have been developed. This methodology might provide a new pathway for directed metal-catalyzed aromatic C-H amination.

SYNTHETIC ANALOGS OF Peganum ALKALOIDS. I. SYNTHESIS OF METHOXY- AND HYDROXY-SUBSTITUTED DEOXYVASICINONES AND DEOXYPEGANINES

6-Methoxy-, 7-methoxy-, and 8-methoxydeoxyvasicinones have been synthesized by the reaction of substituted (3-methoxy-, 4-methoxy-, and 5-methoxy-) anthranilic acids with α-pyrrolidone.The demethylation of these compounds has given the corresponding hydroxy-substituted analogs of deoxyvasicinone, and the reduction of the products obtained with zinc in hydrochloric acid has given the hydroxy- and methoxy- analogs of deoxypeganine. 8-Hydrooxydeoxypeganine dimethyl-, ethyl-, and butylcarbamates have been obtained by the carbamoylation of 8-hydroxydeoxypeganine.