5097-96-1

Basic information

• Product Name: Bis(3-chlorophenyl) sulfide
• Synonyms: Bis(3-chlorophenyl) sulfide
• CAS NO: 5097-96-1
• Molecular Formula: C₁₂H₈Cl₂S
• Molecular Weight: 255.16
• Mol File: 5097-96-1.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Bis(3-chlorophenyl) sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(3-chlorophenyl) sulfide(5097-96-1)
• EPA Substance Registry System: Bis(3-chlorophenyl) sulfide(5097-96-1)

Safety Data

• Hazardous Substances Data: 5097-96-1(Hazardous Substances Data)

Upstream product

• 108-37-2 1-bromo-3-chlorobenzene 
• 456-39-3 3-chlorobenzenediazonium tetrafluoroborate 
• 19742-92-8 bis(3-chlorophenyl) disulfide 

Downstream Products

• 5097-16-5 bis-(3-chloro-phenyl)-sulfone 
• 5097-09-6 3,3'-sulfinylbis(chlorobenzene) 
• 2050-67-1 PCB 11 

Relevant articles and documents

Dechalcogenization of Aryl Dichalcogenides to Synthesize Aryl Chalcogenides via Copper Catalysis

An application for dechalcogenization of aryl dichalcogenides via copper catalysis to synthesize aryl chalcogenides is disclosed. This approach is highlighted by the practical conditions, broad substrate scope, and good functional group tolerance with several sensitive groups such as aldehyde, ketone, ester, amide, cyanide, alkene, nitro, and methylsulfonyl. Furthermore, the robustness of this methodology is depicted by the late-stage modification of estrone and synthesis of vortioxetine. Remarkably, synthesis of more challenging organic materials with large ring tension under milder conditions and synthesis of some halogen contained diaryl sulfides which could not be synthesized using metal-catalyzed coupling reactions of aryl halogen are successfully accomplished with this protocol.

Aryl diazonium salt and thioacetamide: A catalyst free, efficient blend of an inexpensive arylating agent with "s" surrogate for sulphide synthesis

Novel, facile C-S and S-S bond coupling reactions were achieved by using an aryl diazonium salt as an arylating agent and thioacetamide as a sulphur surrogate. The reaction proceeds smoothly at room temperature without using any transition metal catalyst, ligand or base. Aryl diazonium salts undergo rapid reactions with thioacetamide at room temperature to give the desired products in a much shorter period than the previously reported metal catalysed protocols.

Diphenyl ethers for tobacco sucker control

Diphenyl ethers having the formula STR1 WHERE Y and Z are halogen, alkyl, trifluoromethyl, alkoxy, hydroxy, nitro, cyano, carboxy, carbalkoxy, carbamoyl, or alkylthio, and m and n are 0, 1, 2, or 3, Are useful in controlling undesirable secondary growth in plants, particularly sucker growth in tobacco.