51006-81-6

Basic information

• Product Name: (Z)-3,5-dimethyl-3-hexen-1-yne
• CAS NO: 51006-81-6
• Molecular Weight: 108.183
• Mol File: 51006-81-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-3,5-dimethyl-3-hexen-1-yne(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-3,5-dimethyl-3-hexen-1-yne(51006-81-6)
• EPA Substance Registry System: (Z)-3,5-dimethyl-3-hexen-1-yne(51006-81-6)

Safety Data

• Hazardous Substances Data: 51006-81-6(Hazardous Substances Data)

Upstream product

• 107-54-0 3,5-dimethyl-1-hexyn-3-ol 

Relevant articles and documents

Isomerization of propargylic alcohols into α,β-unsaturated carbonyl compounds catalyzed by the sixteen-electron allyl-ruthenium(II) complex [Ru(η3-2-C3H4Me)(CO)(dppf)] [SbF 6]

The 16-e- (η3-allyl)-ruthenium(II) complex [Ru(η3-2-C3H4Me)(CO)(dppf)][SbF 6] is an efficient catalyst for the regioselective isomerization of terminal propargylic alcohols HC≡CCR1R2(OH) into α,β-unsaturated aldehydes R1R2C=CHCHO or ketones R3R4C=C(R1)COMe (if R2 = CHR3R4) under mild conditions. This complex has been also used as catalyst for the preparation of conjugated 1,3-enynes via dehydration of propargylic alcohols.