511302-28-6

Basic information

• Product Name: methyl N-(3-chlorobenzyl)carbamate
• Synonyms: methyl N-(3-chlorobenzyl)carbamate
• CAS NO: 511302-28-6
• Molecular Weight: 199.637
• Mol File: 511302-28-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl N-(3-chlorobenzyl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl N-(3-chlorobenzyl)carbamate(511302-28-6)
• EPA Substance Registry System: methyl N-(3-chlorobenzyl)carbamate(511302-28-6)

Safety Data

• Hazardous Substances Data: 511302-28-6(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 58357-84-9 2-(3-chlorophenyl)acetamide 
• 1529-41-5 3-chloro-benzeneacetonitrile 
• 65398-61-0 O-methyl S-p-bromophenyl thiocarbonate 
• 4152-90-3 m-chlorobenzylamine 
• 3186-52-5 O-methyl-S-phenyl thiolcarbonate 
• 3186-65-0 O-methyl S-p-chlorophenyl thiocarbonate 
• 3186-53-6 O-methyl S-p-methylphenyl thiocarbonate 

Relevant articles and documents

Hypervalent iodine catalyzed hofmann rearrangement of carboxamides using oxone as terminal oxidant

Hofmann rearrangement of carboxamides to carbamates using Oxone as an oxidant can be efficiently catalyzed by iodobenzene. This reaction involves hypervalent iodine species generated in situ from catalytic amount of PhI and Oxone in the presence of 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) in aqueous methanol solutions. Under these conditions, Hofmann rearrangement of various carboxamides affords corresponding carbamates in high yields.