51145-19-8Relevant articles and documents
Palladium-catalyzed decarboxylative acylation of N-nitrosoanilines with α-oxocarboxylic acids
Wu, Yinuo,Sun, Lei,Chen, Yunyun,Zhou, Qian,Huang, Jia-Wu,Miao, Hui,Luo, Hai-Bin
, p. 1244 - 1250 (2016)
A palladium-catalyzed oxidative C-H bond decarboxylative acylation of N-nitrosoanilines using α-oxocarboxylic acid as the acyl source is described. The catalyst Pd(OAc)2 and oxidant (NH4)2S2O8 enabled ortho-acylation of N-nitrosoanilines at room temperature, affording an array of N-nitroso-2-aminobenzophenones in moderate to excellent yields.