51222-09-4

Basic information

• Product Name: C₁₇H₉NO₈
• CAS NO: 51222-09-4
• Molecular Weight: 355.26
• Mol File: 51222-09-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₇H₉NO₈(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₇H₉NO₈(51222-09-4)
• EPA Substance Registry System: C₁₇H₉NO₈(51222-09-4)

Safety Data

• Hazardous Substances Data: 51222-09-4(Hazardous Substances Data)

Upstream product

• 99-31-0 5-aminoisophthalic acid 
• 552-30-7 trimellitic Anhydride 

Relevant articles and documents

Solvation controlling reaction paths and gel-formation in imide derivatives

1,8-Naphthalic anhydride condenses with 4-nitro-1,2-diaminobenzene in acetic acid to give 11-nitrobenzo[d,e]benzo[2,1-a]isoquinoline-1,3-dione (1), whereas the same reaction carried out in DMF gives 2-(2-amino-4-nitrophenyl)-benzo[d,e]isoquinoline-1,3-dione (2). The condensation reaction of 1,8-naphthalic anhydride with 1-amino 3,5-benzene dicarboxylic acid leads to corresponding imide, which forms a gel in a mixed solvent such as water in DMSO. A similar compound 5-(1,3-dioxo-1,3-dihydroisoindol-2-yl)-isophthalic acid derived from phthalic anhydride forms gel in a mixed solvent of DMSO and water, whereas a crystalline solvate of DMSO with 2 could be obtained upon crystallization from DMSO. The crystal structure of this solvate is determined and its structure is compared with 2-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-benzoic acid. The latter does not form a gel in the mixed solvent and adopts an intermolecular hydrogen bonded structure.