51226-42-7

Basic information

• Product Name: 2,4,6-Trinitrobenzamide
• Synonyms: 2,4,6-Trinitrobenzamide
• CAS NO: 51226-42-7
• Molecular Weight: 256.131
• Mol File: 51226-42-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,4,6-Trinitrobenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-Trinitrobenzamide(51226-42-7)
• EPA Substance Registry System: 2,4,6-Trinitrobenzamide(51226-42-7)

Safety Data

• Hazardous Substances Data: 51226-42-7(Hazardous Substances Data)

Upstream product

• 7500-86-9 2,4,6-trinitrobenzoyl chloride 
• 118-96-7 2,4,6-Trinitrotoluene 
• 129-66-8 2,4,6-trinitrobenzoic acid 

Downstream Products

• 292163-55-4 2-Benzylthio-4,6-dinitrobenzamide 
• 321372-52-5 2-benzylsulfonyl-6-benzylthio-4-nitrobenzamide 
• 309272-27-3 (2,4-dinitro-6-phenylmethanesulfonyl-phenyl)-carbamic acid methyl ester 
• 309287-66-9 (2-methoxycarbonylamino-3,5-dinitro-benzenesulfonyl)-acetic acid methyl ester 
• 309286-39-3 (2-carbamoyl-3,5-dinitro-benzenesulfonyl)-acetic acid methyl ester 
• 309286-38-2 (2-methoxycarbonylamino-3,5-dinitro-phenylsulfanyl)-acetic acid methyl ester 
• 335434-43-0 (2-methoxycarbonylamino-5-nitro-benzenesulfonyl)-acetic acid methyl ester 
• 335434-41-8 (2-methoxycarbonylamino-5-nitro-phenylsulfanyl)-acetic acid methyl ester 
• 309272-28-4 2-benzylsulfonyl-4,6-dinitrobenzamide 
• 299920-65-3 methyl 3-amino-4,6-dinitrobenzo[b]thiophene-2-carboxylate 
• 309286-36-0 1-cyano-2,4,6-tris(methoxycarbonylmethylthio)benzene 
• 285553-53-9 2-benzylthio-1-cyano-4,6-dinitrobenzene 
• 906534-05-2 2,4-bis(2,2,2-trifluoroethoxy)-6-(benzylsulfinyl)benzonitrile 
• 906533-87-7 methyl 2-(3,5-bis(p-tolylthio)-2-cyanophenylthio)acetate 

Relevant articles and documents

Synthetic utilization of polynitroaromatic compounds. 1. S-derivatization of 1-substituted 2,4,6-trinitrobenzenes with thiols

Reactions of 1-R-2,4,6-trinitrobenenes (R = alkyl, protected aldehyde, aminocarbonyl, cyano groups, or isoxazole ring) with thiol salts were investigated. In most cases, these reactions gave a mixture of minor para and major ortho substitution products. Reactions of N,N-disubstituted 2,4,6-trinitrobenzamides with S-,O-, and N-nucleophiles afforded products of substitution of the p-nitro group exclusively. 1-Cyano-2,4,6-trinitrobenzene was found to be the most reactive and the least selective: all three nitro groups can be substituted using an excess of thiol salts. 2-R-4,6-dinitrobenzamides showed no regioselectivity under similar conditions to yield 1:1 mixtures of para and ortho isomers.