51244-07-6

Basic information

• Product Name: [Au(ClO₄)(P(C₆H₅)3)]
• Synonyms: [Au(ClO₄)(P(C₆H₅)3)]
• CAS NO: 51244-07-6
• Molecular Weight: 558.708
• Mol File: 51244-07-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: [Au(ClO₄)(P(C₆H₅)3)](CAS DataBase Reference)
• NIST Chemistry Reference: [Au(ClO₄)(P(C₆H₅)3)](51244-07-6)
• EPA Substance Registry System: [Au(ClO₄)(P(C₆H₅)3)](51244-07-6)

Safety Data

• Hazardous Substances Data: 51244-07-6(Hazardous Substances Data)

Upstream product

• 13453-40-2 thallium(I) perchlorate 
• 14243-64-2 chlorotriphenylphosphinegold(I) 
• 14243-64-2 (triphenylphosphine)gold(I) chloride 

Downstream Products

• 265665-81-4 [(1,1'-bis(diphenylthiophosphoryl)ferrocene)Au(PPh₃)]ClO₄ 
• 177427-61-1 [S(AuP(C₆H₅)3)(Au₂C₅H₄P(C₆H₅)2Fe(C₆H₅)2PC₅H₄)]⁽¹⁺⁾*ClO₄^(1-) = [S(AuP(C₆H₅)3)(Au₂C₅H₄P(C₆H₅)2Fe(C₆H₅)2PC₅H₄)]ClO₄ 
• 176251-92-6 S(Au(P(C₆H₅)3))3⁽¹⁺⁾*ClO₄^(1-)=[S(Au(P(C₆H₅)3))3]ClO₄ 
• 200702-41-6 Au(C₁₈H₁₂N₂)(P(C₆H₅)3)⁽¹⁺⁾*ClO₄^(1-) = [Au(C₁₈H₁₂N₂)(P(C₆H₅)3)]ClO₄ 
• 200702-44-9 Au(C₁₁H₈N₂O)(P(C₆H₅)3)⁽¹⁺⁾*ClO₄^(1-) = [Au(C₁₁H₈N₂O)(P(C₆H₅)3)]ClO₄ 
• 200702-48-3 Au(C₁₂H₉N₃)(P(C₆H₅)3)⁽¹⁺⁾*ClO₄^(1-) = [Au(C₁₂H₉N₃)(P(C₆H₅)3)]ClO₄ 
• 200702-46-1 Au(C₁₀H₉N₃)(P(C₆H₅)3)⁽¹⁺⁾*ClO₄^(1-) = [Au(C₁₀H₉N₃)(P(C₆H₅)3)]ClO₄ 
• 200702-22-3 Au(NC₅H₃(CH₃)2)(P(C₆H₅)3)⁽¹⁺⁾*ClO₄^(1-) = [Au(NC₅H₃(CH₃)2)(P(C₆H₅)3)]ClO₄ 
• 200702-33-6 Au(C₁₃H₉N)(P(C₆H₅)3)⁽¹⁺⁾*ClO₄^(1-) = [Au(C₁₃H₉N)(P(C₆H₅)3)]ClO₄ 
• 200702-30-3 Au(C₁₃H₉N)(P(C₆H₅)3)⁽¹⁺⁾*ClO₄^(1-) = [Au(C₁₃H₉N)(P(C₆H₅)3)]ClO₄ 

Relevant articles and documents

Reactivity of (NBu4)[Pt(C6F5)2(acac)] toward electrophilic metal centers: Metal-metal vs metal-Cγ(acac) bond formation. Crystal structure of a complex containing a μ2-acac-O,O′ bridging ligand and a coordinated dichloromethane

The reaction between (NBu4)[Pt(C6F5)2(acac)] and AgClO4 (1:1 molar ratio) in CH2Cl2 at room temperature gives the neutral tetranuclear complex [PtAg(C6F5)2(acac)]2 (1) in a good yield. The structure, which has been determined by single-crystal X-ray diffraction methods, shows two anionic fragments [Pt(C6F5)2(acac)]- linked by two Ag+ atoms, each silver center being bonded to a Pt atom of one fragment and to an oxygen atom of the acac ligand of the other fragment. Noteworthy structural features are the O-acac coordination of the silver atom (instead of the more usual Cγ coordination) and the unexpected presence of a dichloromethane molecule coordinated to the silver center. The reaction of 1 with tht (tht = SC4H8, tetrahydrothiophene) or PPh3 gives the dinuclear complexes [PtAg(C6F5)2(acac)-(L)] (L = tht (2), PPh3 (3)) by cleavage of the O-Ag bond; alternatively, complexes 2 and 3 can be one-pot synthesized by reaction of (NBu4)[Pt(C6F5)2(acac)] and O3ClOAgL (L = tht, PPh3). Their structural characterization points to the presence of donor-acceptor Pt→Ag bonds. Different behavior is observed in the reaction of (NBu4)[Pt(C6F5)2(acac)] with O3-ClOAuPPh3, giving the dinuclear complex [PtAu(μ-acac)(C6F5)2(PPh3)] (4) in which, as can be seen from its spectroscopic data, the gold atom is bonded to Cγ of the acac ligand.

Solid and solution structures of ternary gold(I) complexes with triphenylphosphine and nitrogen-containing ligands

A series of gold(I) complexes [Au(PPh3)L]ClO4 (L = pyridine 1a, 2,6-dimethylpyridine 1b, 2,6-di-tert-butylpyridine 1c, quinoline 1d, acridine 1e, benzo[h]quinoline 1f, naphthyridine 2a, 1,10-phenanthroline 2b, 2,2′-biquinoline 2c, di

SYNTHESIS AND STRUCTURAL CHARACTERISATION OF THE MIXED-METAL CLUSTER CATION 5-C5H4R)2(AuP(C6H5)3)2>+ WITH R = H or Si(CH3)3

Triangular "NbAu2" cluster compounds have been prepared by the reaction of 5-C5H4R)2H3> (R = H, Si(CH3)3) with gold(I) salts and the structure of 5-C5H4Si(CH3)3)2(AuP(C6H5)3)2> PF6 has been determined by X-ray diffraction.