51318-07-1Relevant articles and documents
Titanium Carbene Complexes Stabilized by Alkali Metal Amides
Osseili, Hassan,Truong, Khai-Nghi,Spaniol, Thomas P.,Maron, Laurent,Englert, Ulli,Okuda, Jun
, p. 1833 - 1837 (2019)
Facile α-H elimination from tetrakis(trimethylsilylmethyl)titanium precursors to give adducts of (alkylidene)bis(alkyl)titanium complexes is induced by light alkali metal amides of the NNNN-type macrocyclic anionic ligand Me3TACD [(Me3/su
Rhodium catalyzed reaction of internal alkynes with organoborons under CO atmosphere: a product tunable reaction
Artok, Levent,Ku?, Melih,Aksin-Artok, ?zge,Dege, Fatma Nurcan,?zkilin?, Fatma Yelda
experimental part, p. 9125 - 9133 (2010/01/16)
Alkynes react with organoborons under a CO atmosphere in the presence of a rhodium(I) catalyst to afford mainly 5-aryl-2(5H)-furanones, α,β-unsaturated ketones, and indanones. The product selectivity can be tuned by modifying the reaction conditions.
Diethylaluminum chloride mediated vinylsilane synthesis: Comparison of different solvent systems
Kwan, Man Lung,Battiste, Merle A.,Macala, Megan K.,Aybar, Sylvia C.,James, Nicholas C.,Haoui, Joseph J.
, p. 1943 - 1950 (2007/10/03)
Aromatic ketones were converted to one-carbon elongated-vinylsilanes in a convenient one-pot operation via the Peterson protocol. Reactions were conducted in two different solvents for comparison: pentane and triethylamine. Results indicate that triethylamine appeared to be a more suitable solvent for such a transformation producing vinylsilanes with great chemo- and stereo-selectivity than pentane.
