51479-97-1

Basic information

• Product Name: Benzenamine, N,N'-1,2-ethanediylidenebis[2-methyl-
• CAS NO: 51479-97-1
• Molecular Formula: C16H16N2
• Molecular Weight: 236.316
• Mol File: 51479-97-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzenamine, N,N'-1,2-ethanediylidenebis[2-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N,N'-1,2-ethanediylidenebis[2-methyl-(51479-97-1)
• EPA Substance Registry System: Benzenamine, N,N'-1,2-ethanediylidenebis[2-methyl-(51479-97-1)

Safety Data

• Hazardous Substances Data: 51479-97-1(Hazardous Substances Data)

Upstream product

• 95-53-4 o-toluidine 
• 131543-46-9 Glyoxal 

Downstream Products

• 84312-61-8 1,4-Di-o-tolyl-1,4,4a,7a-tetrahydro-furo[3,4-b]pyrazine-5,7-dione 
• 1005483-78-2 (2-MeC₆H₄NCH₂C(CH₂Ph)C₆H₄Me-2)Hf(CH₂Ph)3 
• 94-92-8 1,2-bis[(2-methylphenyl)amino]ethane 
• 848189-26-4 [tris(1-(2-naphthoyl)-3,3,3-trifluoroacetonate)(1,4-bis(o-tolyl)-1,4-diaza-1,3-butadiene)europium(III)] 
• 848189-28-6 [tris(1-(2-naphthoyl)-3,3,3-trifluoroacetonate)(1,4-bis(o-tolyl)-1,4-diaza-1,3-butadiene)gadolinium(III)] 
• 405316-13-4 [(CH₃C₆H₄NCHCHNC₆H₄CH₃)C₅(CH₃)5ClIr]⁽¹⁺⁾*PF₆^(1-)=[(CH₃C₆H₄NCHCHNC₆H₄CH₃)C₅(CH₃)5ClIr]PF₆ 
• 101957-99-7 carbonylchloroglyoxalbis(2-methylphenylimine)rhodium(I) 
• 51480-06-9 2,3-Bis-[(E)-o-tolylimino]-succinonitrile 
• 51480-03-6 3-[(Z)-o-Tolylimino]-2-[(E)-o-tolylimino]-propionitrile 
• 84312-71-0 6-Benzyl-1,4-di-o-tolyl-1,4,4a,7a-tetrahydro-pyrrolo[3,4-b]pyrazine-5,7-dione 
• 614-68-6 2-tolyl isocyanate 

Relevant articles and documents

Synthesis of pentafluorobenzene-based NHC adducts and their catalytic activity in the microwave-assisted reactions of aldehydes

N-Heterocyclic carbenes (NHCs) have been widely used in organometallic chemistry as ligands, as well as standalone organocatalysts in various reactions, mostly using aromatic aldehydes as substrates. We have previously demonstrated the efficiency of azolium-2-carboxylate zwitterions in the hydroxymethylation of aldehydes, especially aliphatic aldehydes, under microwave irradiation. In the present work, we report a series of pentafluorobenzene-based NHC adducts and their efficiency in the hydroxymethylation and self-condensation of aliphatic and aromatic aldehydes using microwave irradiation. The free carbenes are released under the reaction conditions and 1,3-dimesityl-2-(perfluorophenyl)imidazolidine and 1,3-bis(2,6-dimethylphenyl)-2-(perfluorophenyl)imidazolidine proved to be the most potent precatalysts.

Synthesis of 1,4-diazabutadienes (=N,N′-ethane-1,2- diylidenebis[amines]) by grinding

A simple and convenient method for the synthesis of 1,4-diazabutadienes (=N,N′-ethane-1,2-diylidenebis[amines]) by grinding glyoxal (=ethanedial) or an α-diketone and anilines (=benzenamines) in the presence of TsOH in a mortar with a pestle is described.