51507-36-9

Basic information

• Product Name: Benzene, 1,1'-(3-methyl-2-butenylidene)bis-
• CAS NO: 51507-36-9
• Molecular Formula: C17H18
• Molecular Weight: 222.33
• Mol File: 51507-36-9.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(3-methyl-2-butenylidene)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(3-methyl-2-butenylidene)bis-(51507-36-9)
• EPA Substance Registry System: Benzene, 1,1'-(3-methyl-2-butenylidene)bis-(51507-36-9)

Safety Data

• Hazardous Substances Data: 51507-36-9(Hazardous Substances Data)

Upstream product

• 110835-94-4 2,2-dimethyl-4,4-diphenylbut-3-enoic acid 
• 124-68-5 2-Amino-2-methyl-1-propanol 
• 591-50-4 iodobenzene 
• 556-82-1 3-methyl-2-buten-1-ol 
• 91-01-0 1,1-Diphenylmethanol 
• 75-65-0 tert-butyl alcohol 
• 28567-35-3 (tert-butoxymethylene)dibenzene 
• 574-42-5 benzhydryl ether 
• 947-91-1 Diphenylacetaldehyde 
• 24470-78-8 isopropyltriphenylphosphonium iodide 
• 1694-31-1 tert-butyl acetoacetate 
• 18292-39-2 (2-methyl-1-propen-1-yl)trimethylsilane 
• 30979-52-3 1-methyl-2,2-diphenylbicyclobutane 
• 90-99-3 diphenylchloromethane 

Downstream Products

• 6240-49-9 1,1-dimethyl-3-phenyl-2,3-dihydro-1H-indene 

Relevant articles and documents

Direct Synthesis of Indanes via Iron-Catalyzed Dehydrative Coupling/Friedel–Crafts Cyclization of Two Different Alcohols

We report herein a novel iron-catalyzed cascade dehydrative coupling/Friedel–Crafts cyclization of two different alcohols, providing a variety of indanes, which are ubiquitous substructures found in natural products, pharmaceuticals, and functional materi

Metal-Free Dehydrogenative Diels-Alder Reactions of Prenyl Derivatives with Dienophiles via a Thermal Reversible Process

An efficient dehydrogenative Diels-Alder reaction of prenyl derivatives with dienophiles has been developed. The reaction exhibits broad substrate scope and provides efficient access to cyclohexene derivatives with good to excellent yields. A reasonable mechanism involving a metal-free thermal reversible process is proposed.

Enantiospecific, regioselective cross-coupling reactions of secondary allylic boronic esters

An original syn: The first enantioselective Suzuki-Miyaura cross-coupling of chiral, enantioenriched secondary allylic boronic esters is described (see scheme; DME=dimethoxyethane, Bpin = pinacolboryl, dba = dibenzylideneacetone). Mechanistic studies show that the reactions proceed via γ-selective transmetalation followed by reductive elimination. The reaction provides the first independent confirmation that the transmetalation of boronic esters proceeds via a syn pathway. Copyright