51525-37-2

Basic information

• Product Name: Silane, methoxybis(2,4,6-trimethylphenyl)-
• CAS NO: 51525-37-2
• Molecular Formula: C19H26OSi
• Molecular Weight: 298.5
• Mol File: 51525-37-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, methoxybis(2,4,6-trimethylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, methoxybis(2,4,6-trimethylphenyl)-(51525-37-2)
• EPA Substance Registry System: Silane, methoxybis(2,4,6-trimethylphenyl)-(51525-37-2)

Safety Data

• Hazardous Substances Data: 51525-37-2(Hazardous Substances Data)

Upstream product

• 85656-15-1 C₃₁H₃₈OSi 
• 67-56-1 methanol 
• 79184-71-7 dimesitylsilylene 
• 75529-57-6 1,1-dimesityl-2,3-bis(trimethylsilyl)-1-silacyclopropene 
• 75529-54-3 1,1-dimesityl-1-((trimethylsilyl)ethynyl)trimethyldisilane 

Relevant articles and documents

Reactions of Oxasilacyclopropane. Generation of Silanediyl by Photo and Thermal Induced Cycloelimination

Dimesitylsilanediyl was generated from photolysis and pyrolysis of the oxasilacyclopropane (1) via a 2 + 1> cycloelimination reaction.

PHOTOLYSIS OF ORGANOPOLYSILANES. THE SYNTHESIS AND REACTIONS OF STABLE SILACYCLOPROPENES

Two stable silacyclopropenes, 1,1-dimensityl-2,3-bis(trimethylsilyl)-1-silacyclopropene and 1,1-dimesityl-2-phenyl-3-trimethylsilyl-1-silacyclopropene, have been prepared by photolysis of 1,1-dimesityl-1-trimethylsilylethynyltrimethyldisilane and 1,1-dimesityl-1-phenylethynyldisilane, respectively.It has been found that these silacyclopropenes are not affected by atmospheric oxygen, moisture and alcohols at room temperature. 1-Mesityl-1-methyl-2-phenyl-3-trimethylsilyl-1-silacyclopropene prepared by the photolyisis of 1-mesityl-1-phenylethynyltetramethyldisilane is rather stable toward atmospheric oxygen, but reacts readily with methanol in benzene to give a ring-opening methoxysilane.Photochemical and thermal behavior of these silacyclopropenes has been investigated.